Adsorbent-Based Refrigerant Leakage Detection

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Solution Overview

Problem

Current methods fail to efficiently detect refrigerant leakage in refrigerating systems within a short time frame, especially at extremely low concentrations, and are hindered by interference from other gas-emitting substances, posing risks to the apparatus during testing.

Innovation Solution

A method involving the use of an adsorbent to selectively accumulate refrigerant gas, followed by desorption and analysis using a gas sensor like a mass spectrometer, allowing for reliable detection and quantification of refrigerant leakage without disrupting manufacturing cycles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If local checking of potential leak sites using a sniffer is performed, then leakage can be detected, but the operator's care and attention are extremely demanded and the process is time-consuming

Engineering Contradiction:
Improveleakage detection capabilityVSAvoidoperator's care and attention
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The system performs automatic sampling and analysis without requiring operator intervention. The sampling device automatically draws air through the refrigerating system, and the gas analyzer automatically detects refrigerant concentrations, eliminating the need for operator skill and attention in manual sniffer operations

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The manual mechanical sniffer operation is replaced with an automated electronic gas analyzer system that uses optical or electrical detection methods to measure refrigerant concentrations, substituting human operator skill with automated instrumentation

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If bubble test in immersion test is performed, then leakage can be detected, but irreversible damage to the apparatus may occur

Engineering Contradiction:
Improveleakage detection capabilityVSAvoiddamage to apparatus
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The harmful immersion test process is replaced by extracting only the air sample through the refrigerating system using a sampling device, without submerging or contacting the apparatus with liquid, thereby eliminating the risk of irreversible damage while still enabling leakage detection

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

A sampling device acts as an intermediary to draw air through the refrigerating system, separating the detection function from the apparatus itself. This intermediary approach allows gas sampling without direct contact between test media and the apparatus, preventing damage

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If refrigerant leakage is detected at extremely low concentrations in the ppb range within a very short time span, then fast leak detection is achieved, but the measurement complexity increases

Engineering Contradiction:
Improveleak detection speedVSAvoidmeasurement system complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The measurement process is segmented into distinct functional modules: a sampling device for air intake, a gas analyzer for refrigerant detection, and a processing system for data evaluation. This segmentation allows each component to be optimized independently, achieving fast ppb-range detection without overwhelming overall system complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The gas analyzer is designed to perform multiple functions: sampling air, analyzing refrigerant concentration at ppb levels, and providing leak rate calculation. This multi-functionality consolidates what would otherwise require separate complex systems into a single integrated device, reducing overall measurement complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Measurement precision

If other gas-emitting hydrocarbons are present in the environment, then background interference occurs, but selective measurement of the refrigerant becomes difficult

Engineering Contradiction:
Improverefrigerant detection accuracyVSAvoidbackground interference from hydrocarbons
Core Design Contradiction:
Measurement precisionVSObject-generated harmful factors

Solution Approach 1:

The gas analyzer is equipped with selective detection capability that identifies refrigerants based on their specific physical or chemical properties (such as mass-to-charge ratio in mass spectrometry or specific absorption characteristics). This local quality approach allows the system to distinguish refrigerant molecules from other gas-emitting hydrocarbons in the complex environmental background

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The system changes the detection parameter to be specific to refrigerants (such as molecular mass, infrared absorption frequency, or other refrigerant-specific characteristics) rather than using general gas detection. This parameter specialization enables selective measurement that ignores interfering hydrocarbons with different physical or chemical properties

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables rapid and accurate detection of refrigerant leakage even at low concentrations, suppressing interference gases and preventing apparatus damage, thus facilitating efficient integration into manufacturing lines.

Implementation Method 1

the ambient gas is passed from the environment of the apparatus across or through an adsorbent that adsorbs the condensable gas

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

the adsorbent is excited to desorb the adsorbed gas

Methodology Applied
Scientific EffectDesorption: Desorption

Implementation Method 3

the excitation for the desorption of the adsorbed gas is performed, e.g. by heat radiation

Methodology Applied
Scientific EffectHeat radiation: Thermal Radiation

Data Source

PatentUS8899099B2Method and device for determining leakage
Publication Date: 2014.12.02 INFICON GMBH
  • US8899099B2 patent drawing
  • US8899099B2 patent drawing

AI summary

In order to determine leakage on a device, which contains gas that can be condensed, an adsorbent is used through which ambient gas of the object is conducted. The adsorbed gas is desorbed by means of actuating an excitation device and fed to a gas sensor containing a mass spectrometer. In this way, minute amounts of leaking gas can be determined by means of accumulation. The method is in particular suited for use in the serial production of refrigeration machines.