Adsorbent Saccharide Complex Crystallization Suppression

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Solution Overview

Problem

Adsorbents containing diatomaceous earth and a basic compound experience a decrease in adsorption performance due to crystallization of the basic compound, which reduces the effective surface area for acid gas adsorption.

Innovation Solution

Incorporating a saccharide, such as glucose, into the adsorbent composition, along with diatomaceous earth and an alkali metal carbonate as the basic compound, to suppress crystallization and maintain adsorption performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a basic compound is supported on diatomaceous earth to create an adsorbent, then the adsorbent can remove acid gases, but the basic compound undergoes crystallization which decreases the effective surface area and reduces adsorption performance

Engineering Contradiction:
Improveadsorption performanceVSAvoideffective surface area
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

A saccharide is introduced as an intermediary substance between the basic compound and diatomaceous earth. The saccharide forms a complex with the basic compound that prevents crystallization, thereby maintaining the effective surface area while preserving acid gas adsorption capability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The chemical state of the basic compound is changed by forming a complex with saccharide. This parameter change prevents the basic compound from undergoing crystallization, thereby maintaining its adsorption performance over time

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If the basic compound is used in high concentration to enhance adsorption capacity, then more acid gas can be adsorbed, but crystallization occurs more readily which reduces effective surface area

Engineering Contradiction:
Improvebasic compound contentVSAvoidadsorption performance
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The saccharide acts as a mediator that allows higher concentrations of basic compound to be used without triggering crystallization. The complex formed between saccharide and basic compound remains stable even at high basic compound concentrations, preventing the harmful crystallization effect

Inventive Principle:
Principle #24Intermediary (Mediator)

3Duration of action of moving object

If the adsorbent is used for extended periods to maximize utilization, then operational efficiency improves, but the basic compound crystallizes over time which decreases adsorption performance

Engineering Contradiction:
Improveadsorbent lifespanVSAvoidadsorption performance
Core Design Contradiction:
Duration of action of moving objectVSReliability

Solution Approach 1:

The saccharide is incorporated into the adsorbent structure in advance, creating a preliminary protective complex with the basic compound. This preliminary action prevents crystallization from occurring during extended use, thereby maintaining adsorption performance throughout the adsorbent's lifespan

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The saccharide serves as a long-term intermediary that continuously prevents crystallization of the basic compound during extended operational periods, ensuring stable adsorption performance over time

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The addition of a saccharide effectively suppresses the crystallization of the basic compound, maintaining the adsorption performance of the adsorbent for acid gases like sulfur dioxide and hydrogen sulfide, and extending its lifespan.

Implementation Method 1

when the basic compound undergoes crystallization, the effective surface area in which a reaction with an acid gas to be adsorbed is caused decreases

Methodology Applied
Scientific EffectCrystallization suppression: Crystallisation

Implementation Method 2

an adsorbent for adsorbing an acid gas

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20250135433A1Adsorbent and method for producing adsorbent
Publication Date: 2025.05.01 DAIKIN INDUSTRIES LTD
  • US20250135433A1 patent drawing
  • US20250135433A1 patent drawing

AI summary

[Object] To suppress a decrease in the adsorption performance of an adsorbent containing diatomaceous earth and a basic compound.[Solution] An adsorbent for adsorbing an acid gas contains diatomaceous earth, a basic compound, and a saccharide.