Adsorptive Filter Material for Acid Removal

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing materials, particularly those based on activated carbon and ion-exchange resins, are inefficient in removing acids and acid-forming substances from air due to poor sorption performance, co-adsorption of organic substances, and unwanted chemical reactions, which limits their use in industrial and personal protection applications.

Innovation Solution

A filter material comprising at least 60% strong alkaline quaternary anion exchange resin in the hydro-carbonate form and no more than 15% cation exchange resin in the H-form, with a water content of 25% bound in the polymer matrix, which enhances adsorption efficiency without releasing trace elements or forming odorous substances.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If activated carbon is used for acid removal, then adsorption capacity is improved, but co-adsorption of organic substances occurs reducing effectiveness

Engineering Contradiction:
Improveacid removal capacityVSAvoidco-adsorption of organic substances
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by creating a heterogeneous adsorbent composition with distinct functional regions: hydrophilic adsorbent materials (such as silica gel, alumina, or molecular sieves) are positioned to specifically interact with acidic gases, while hydrophobic components are excluded or minimized. This localized functional differentiation ensures that the adsorption sites are selectively tuned for acid removal without the non-specific co-adsorption characteristic of activated carbon.

Inventive Principle:
Principle #3Local quality

2Quantity of substance

If activated carbon is used for acid removal, then adsorption capacity is improved, but transport kinetics are slow reducing performance

Engineering Contradiction:
Improveacid removal capacityVSAvoidsorption performance
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent utilizes porous materials with optimized pore structures such as silica gel, alumina, or molecular sieves that provide high surface area and efficient mass transport pathways. These materials feature controlled pore sizes and distributions that facilitate rapid diffusion of acidic gases to active adsorption sites, overcoming the slow transport kinetics inherent in activated carbon systems while maintaining high acid removal capacity.

Inventive Principle:
Principle #31Porous materials

3Quantity of substance

If activated carbon is used for acid removal, then adsorption capacity is improved, but surface reactions create harmful substances

Engineering Contradiction:
Improveacid removal capacityVSAvoidunwanted chemical reactions
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent creates an inert chemical environment by selecting adsorbent materials such as silica gel, alumina, or molecular sieves that are chemically stable and resistant to unwanted surface reactions. These materials do not catalyze the conversion of harmless substances into corrosive forms, thereby preventing the formation of harmful byproducts while maintaining effective acid removal through physical adsorption and chemisorption mechanisms.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

4Quantity of substance

If ion-exchange resins are used for acid removal, then adsorption efficiency is improved, but release of odorous substances occurs

Engineering Contradiction:
Improveacid adsorption efficiencyVSAvoidodor release
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and eliminates the problematic functional groups from ion-exchange resins that cause odorous substance release. Instead of using traditional amine-functionalized resins that decompose to release volatile organic compounds, the invention employs alternative adsorbent materials such as hydrophilic porous materials or modified silica gel that provide acid removal functionality without the decomposition and odor generation associated with conventional ion-exchange resins.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The material achieves high adsorption efficiency for acids and acid-forming substances, maintaining performance over extended periods without odor release, suitable for industrial and personal protection applications.

Implementation Method 1

a filter material (1) comprising at least 60% of a strong alkaline quaternary anion exchange resin in the hydro-carbonate form

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

strong alkaline quaternary anion exchange resin in the hydro-carbonate form

Methodology Applied
Scientific EffectIon Exchange: Ion Exchange

Data Source

PatentUS7887619B2Adsorptive filter material
Publication Date: 2011.02.15 ARTEMIS CONTROL

AI summary

An adsorptive filter material for the adsorption of acids or acid forming substances from the air is presented, which comprises an ion exchange material. The ion exchange material comprises a strong alkaline anion exchange resin with a ratio of at least 60% in the hydrogencarbonate form and a cation exchange resin in the H form with a ratio of not more than 15%.