Aerogel-Embedded Liquid Crystal Optical Device

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Solution Overview

Problem

Existing optical devices with variable refractive indices, especially in eyewear, require polarizers due to the birefringence of liquid crystals, which are costly and reduce transparency, making them unsuitable for ophthalmic use, and alternative solutions like cholesteric liquid crystals are difficult to orient and light-diffusing.

Innovation Solution

An optical device comprising an aerogel with an encapsulating structure and embedded optically non-isotropic liquid crystals, where electrodes generate an electrical field to orient the liquid crystals, changing the refractive index without the need for polarizers, utilizing a high porosity aerogel to maintain transparency and prevent cracking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If liquid crystals are used to achieve variable refractive index, then the refractive index can be changed, but polarizers are required which increase cost and decrease transparency

Engineering Contradiction:
Improverefractive index variabilityVSAvoidtransparency and cost-effectiveness
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The invention extracts and removes the polarizer component from the liquid crystal system. By using a specific liquid crystal composition with high birefringence and appropriate thickness, the device achieves variable refractive index without requiring polarizers, thereby eliminating the associated cost and transparency reduction.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the parameters of the liquid crystal system by selecting specific materials with high birefringence (Δn ≥ 0.2) and controlling the layer thickness (d ≥ 10 μm). These parameter changes enable the system to achieve sufficient optical modulation without polarizers, resolving the contradiction between refractive index variability and transparency.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If cholesteric liquid crystals are used to eliminate polarizers, then polarizer-free operation is achieved, but the material becomes light-diffusing and difficult to orient

Engineering Contradiction:
Improvepolarizer-free operationVSAvoidlight transmission quality
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The invention changes the material parameters by selecting nematic liquid crystals with high birefringence instead of cholesteric liquid crystals. This parameter change maintains polarizer-free operation while avoiding the light-diffusing properties of cholesteric phases, achieving both goals simultaneously.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If polymer dispersed crystal liquids are used as polarizer-free alternative, then polarizers are eliminated, but the layers become light-diffusing and insufficient crystal liquids are present for satisfactory refractive index change

Engineering Contradiction:
Improvepolarizer-free operationVSAvoidrefractive index change capability
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The invention uses a porous support structure with controlled porosity (30-80%) to embed the liquid crystal material. This porous architecture provides sufficient volume for adequate liquid crystal content while maintaining optical transparency, enabling both polarizer-free operation and satisfactory refractive index change.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention creates a composite material system combining a porous support matrix with liquid crystal material. This composite structure allows the liquid crystal to be distributed throughout the porous network, providing sufficient total liquid crystal volume for refractive index modulation while the porous structure maintains optical clarity.

Inventive Principle:
Principle #40Composite materials

4Illumination intensity

If high porosity aerogel is used to maintain transparency and enable high liquid crystal content, then transparency and tunability are improved, but the structure becomes more complex and vulnerable to cracking

Engineering Contradiction:
ImprovetransparencyVSAvoidstructural complexity and crack resistance
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The invention employs aerogel, an ultralight porous material with porosity exceeding 75%, as the support structure. This material provides exceptional transparency due to its low density and minimal light scattering, while its porous network accommodates high liquid crystal content for enhanced refractive index tunability.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention applies a protective encapsulating coating to the aerogel structure before liquid crystal infiltration. This pre-applied protective layer cushions the fragile aerogel against mechanical stress and prevents cracking during subsequent processing and device operation, addressing the vulnerability issue beforehand.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device achieves a significant change in refractive index while remaining transparent and polarizer-free, with the aerogel's high porosity allowing for high tunability and protection from environmental strains, suitable for applications like spectacle lenses with adjustable optical correction.

Implementation Method 1

Aerogels are ultraporous materials, the porosity of which typically reaches at least 75% of their volume

Methodology Applied
Scientific EffectPorosity: Porosity

Implementation Method 2

the aerogel porosities being small enough to induce a steric constraint on the optically non isotropic material molecules, thus preventing these to orient each other when they are not submitted to any electrical field

Methodology Applied
Scientific EffectSteric constraint:

Implementation Method 3

Electrodes are arranged in order to be able to generate an electrical field in the encapsulating structure embedding the optically non isotropic material, thus orienting the latter and modifying the overall refractive index of the optical device

Methodology Applied
Scientific EffectElectrical field: Electric Field

Implementation Method 4

optical devices with a variable refractive index... integrate liquid crystals, which orientation and optical properties change when these are submitted to an electrical field

Methodology Applied
Scientific EffectBirefringence: Birefringence

Implementation Method 5

The encapsulating structure allows protecting the aerogel of the present invention from the open air, since cracks are very much unsuited in most optical devices

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Data Source

PatentEP3746821B1Phase change optical device
Publication Date: 2022.11.30 ESSILOR INTERNATIONAL(COMPAGNIE GENERALE D OPTIQUE)
  • EP3746821B1 patent drawingFigure 1~3
  • EP3746821B1 patent drawingFigure 4a~4d
  • EP3746821B1 patent drawing

AI summary

Optical device comprising: - an aerogel located in an encapsulating structure, - an optically non isotropic material presenting a refractive index which can be changed upon submitting said material to an electrical field, preferentially a liquid crystal mixture, embedded in the aerogel, and - a first and a second electrodes arranged to generate an electric field in the encapsulating structure.