Polyimide Aerogel Laminate Panels Balancing Strength and Density

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Solution Overview

Problem

Aerospace panels face challenges in designing durable yet lightweight materials that can withstand extreme environmental stresses while maintaining optimal thermal insulation and structural support, with existing materials failing to balance strength, thermal conductivity, and density effectively.

Innovation Solution

The development of laminate panels comprising a polyimide-based aerogel layer with a facesheet and a reflective protection layer, where the aerogel layer is optimized for specific properties such as flexural strength, modulus, density, and thermal conductivity, and can be reinforced with fibers and opacifiers to enhance structural and insulating capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If traditional structural materials are used to provide strength and durability, then mechanical strength is improved, but density and weight increase

Engineering Contradiction:
Improveflexural strengthVSAvoiddensity
Core Design Contradiction:
StrengthVSWeight of moving object

Solution Approach 1:

The patent employs a composite structure consisting of a polyimide aerogel core layer combined with facesheets and reflective protection layers. The aerogel provides exceptional strength-to-density ratio, while the composite architecture integrates multiple materials to simultaneously achieve high flexural strength and low density, resolving the contradiction between structural durability and weight reduction in aerospace applications

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes polyimide aerogel, a highly porous material with controlled pore structures, as the core insulating layer. The porous architecture provides both mechanical strength and extremely low density (typically 0.01-0.3 g/cm³), enabling the panel to achieve high strength-to-weight ratio while maintaining superior thermal insulation properties

Inventive Principle:
Principle #31Porous materials

2Loss of energy

If thick insulating layers are used to reduce thermal conductivity, then thermal insulation is improved, but panel thickness and weight increase

Engineering Contradiction:
Improvethermal conductivityVSAvoidpanel thickness
Core Design Contradiction:
Loss of energyVSLength of stationary object

Solution Approach 1:

The patent employs polyimide aerogel with a highly porous structure featuring sub-nanometer to nanometer-scale pores. This porous architecture dramatically reduces thermal conductivity by minimizing conduction pathways and eliminating convection, achieving superior thermal insulation with minimal thickness. The aerogel's low density and high porosity allow thick insulating performance in a thin profile

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent applies different material properties to different layers: the aerogel core provides extreme thermal insulation with minimal thickness, while facesheets and reflective layers provide structural support and radiation barrier functions. This localized optimization of material properties achieves comprehensive thermal protection without requiring uniform thickness increases throughout the panel

Inventive Principle:
Principle #3Local quality

3Weight of moving object

If lightweight materials are used to reduce density, then weight is reduced, but mechanical strength and durability decrease

Engineering Contradiction:
ImprovedensityVSAvoiddurability
Core Design Contradiction:
Weight of moving objectVSReliability

Solution Approach 1:

The patent creates a composite panel structure where the polyimide aerogel core provides lightweight insulation, while external facesheets and reflective protection layers provide structural strength and environmental durability. This composite architecture allows the lightweight aerogel to be protected from mechanical damage, moisture, and UV degradation, maintaining both low weight and high reliability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent incorporates protective facesheets and reflective layers that shield the fragile aerogel material from mechanical damage, environmental exposure, and degradation before such damage can occur. This protective architecture ensures the lightweight aerogel maintains its performance and durability throughout the service life of the aerospace component

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The laminate panels achieve a balance of high flexural strength, low thermal conductivity, and low density, making them suitable for aerospace applications by providing effective insulation and structural support while minimizing weight and energy consumption.

Implementation Method 1

Aerogels function as thermal insulators primarily by minimizing conduction (low density, tortuous path for heat transfer through the nanostructures), convection (very small pore sizes minimize convection)

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 2

Aerogels function as thermal insulators primarily by minimizing conduction (low density, tortuous path for heat transfer through the nanostructures)

Methodology Applied
Scientific EffectConduction: Conduction (thermal)

Implementation Method 3

Supercritical and subcritical fluid extraction technologies are used to extract the fluid from the gel without causing the collapse of the pores

Methodology Applied
Scientific EffectSupercritical fluid extraction: Supercritical Fluid Extraction

Implementation Method 4

Supercritical and subcritical fluid extraction technologies are used to extract the fluid from the gel

Methodology Applied
Scientific EffectFluid extraction: Liquid-Liquid Extraction

Implementation Method 5

a reflective protection layer on the facesheet

Methodology Applied
Scientific EffectReflection: Reflection

Data Source

PatentUS11760837B2Aerogel compositions and manufacturing thereof
Publication Date: 2023.09.19 ASPEN AEROGELS INC
  • US11760837B2 patent drawing
  • US11760837B2 patent drawing
  • US11760837B2 patent drawing

AI summary

The present invention provides compositions and methods related to aerogel materials, including polyimide-based aerogels. In particular, aerogel materials optimized to have certain physical and chemical properties such as flexural and compressive strength are provided. In some embodiments, the aerogel materials can be at least partially carbonized.