Low Temperature Aerosol Deposition for Plasma Resistive Layers

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Solution Overview

Problem

Conventional high-temperature coating methods for semiconductor processing chamber components result in poor uniformity, surface cracks, and reduced lifespan due to corrosive plasma exposure, leading to increased maintenance and contamination.

Innovation Solution

A low-temperature aerosol deposition method using an aerosol generator to form a plasma resistive layer from fine particles, typically rare earth metals like yttrium oxide, at substrate temperatures between 0°C and 50°C, ensuring uniformity and strong bonding without thermal damage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional high-temperature coating methods are used, then sufficient thermal energy is provided to deposit material, but surface uniformity deteriorates and cracks form

Engineering Contradiction:
Improvethermal energyVSAvoidsurface uniformity
Core Design Contradiction:
Use of energy by moving objectVSManufacturing precision

Solution Approach 1:

The invention changes the temperature parameter from conventional high-temperature processing to low-temperature processing (below 100°C, preferably below 50°C). This parameter change allows material deposition without the thermal damage that causes cracking and non-uniformity, while still achieving sufficient bonding through the aerosol deposition mechanism

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces thermal energy-driven deposition with a mechanical aerosol deposition system. The aerosol generator creates fine particles that are transported and deposited on the substrate through fluid dynamics and kinetic energy rather than thermal energy, eliminating the need for high temperature while maintaining deposition effectiveness

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Quantity of substance

If conventional high-temperature coating methods are used, then material deposition is achieved, but component lifespan reduces due to thermal damage

Engineering Contradiction:
Improvecoated materialVSAvoidcomponent lifespan
Core Design Contradiction:
Quantity of substanceVSDuration of action of stationary object

Solution Approach 1:

By changing the temperature parameter to low-temperature processing, the invention prevents thermal damage to the substrate and underlying layers, thereby extending component lifespan while still achieving complete material deposition through the aerosol mechanism

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses an aerosol of fine particles that can be easily generated and controlled. The low-temperature process prevents degradation of both the substrate and the deposited layer, creating a more durable coating system that extends component service life

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If conventional coating methods are used, then protective layer is formed, but microcracks develop over time

Engineering Contradiction:
Improveprotective layer formationVSAvoidmicrostructure integrity
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The low-temperature parameter change prevents thermal stress and microcrack formation during deposition. The gradual, controlled deposition of aerosol particles creates a more stable and crack-free microstructure compared to rapid high-temperature deposition

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The aerosol generator prepares fine particles in advance, allowing for controlled, uniform deposition that prevents microcrack formation. The preliminary formation of the aerosol ensures consistent particle size and distribution, leading to a more stable coating structure

Inventive Principle:
Principle #10Preliminary action

4Quantity of substance

If high-temperature processing is used, then material deposition is sufficient, but surface properties deteriorate

Engineering Contradiction:
Improvedeposited materialVSAvoidsurface properties
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

Changing from high-temperature to low-temperature processing preserves surface properties such as smoothness, uniformity, and material characteristics. The low-temperature aerosol deposition achieves sufficient material quantity without the surface degradation caused by thermal exposure

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method provides a robust, uniform plasma resistive layer that enhances corrosion resistance, reduces chamber downtime, and increases the lifespan of semiconductor processing chamber components by preventing corrosive plasma attack and minimizing particulate contamination.

Implementation Method 1

forming an aerosol of fine particles in an aerosol generator, dispensing the aerosol from the generator into a processing chamber and toward a surface of a substrate

Methodology Applied
Scientific EffectAerosol deposition: Aerosol

Implementation Method 2

depositing a layer from material in the aerosol on the substrate surface

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS7479464B2Low temperature aerosol deposition of a plasma resistive layer
Publication Date: 2009.01.20 APPLIED MATERIALS INC
  • US7479464B2 patent drawing
  • US7479464B2 patent drawing
  • US7479464B2 patent drawing

AI summary

Embodiments of the present invention provide a method for low temperature aerosol deposition of a plasma resistive layer on semiconductor chamber components/parts. In one embodiment, the method for low temperature aerosol deposition includes forming an aerosol of fine particles in an aerosol generator, dispensing the aerosol from the aerosol generator into a processing chamber toward a surface of a substrate, maintaining the substrate temperature at between about 0 degrees Celsius and 50 degrees Celsius, and depositing a layer from material in the aerosol on the substrate surface.