AFA Microalgae Extraction for Bioactive Concentration

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Solution Overview

Problem

Current methods for extracting and utilizing the bioactive components from Aphanizomenon Flos Aquae (AFA) microalgae lack efficient processes to concentrate its unique phycobiliproteins, phytochrome, and mycosporine-like amino acids, limiting their antioxidant, anti-inflammatory, and antitumor properties in nutritional, cosmetic, and pharmaceutical applications.

Innovation Solution

Aqueous extraction process involving centrifugation, size exclusion separation, and ultrafiltration to concentrate C-phycocyanin, phycoerythrocyanin, and phytochrome, combined with ethanol extraction for lipophilic components, resulting in high-concentration extracts that enhance the bioactive properties of AFA-phycocyanins and other molecules.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional extraction methods are used for AFA microalgae, then the extraction process is simple, but the concentration of bioactive components (phycobiliproteins, phytochrome, mycosporine-like amino acids) is insufficient

Engineering Contradiction:
Improveconcentration of bioactive componentsVSAvoidextraction process complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The extraction process is divided into multiple sequential stages: cell disruption, centrifugation to separate supernatant from precipitate, size exclusion chromatography, and ultrafiltration. Each stage targets specific bioactive components, progressively concentrating them while removing interfering substances. This segmentation enables achieving high concentration of multiple bioactive components simultaneously.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent systematically extracts different bioactive components from AFA microalgae through selective procedures. Water-soluble components (phycobiliproteins, phytochrome) are extracted from the supernatant, while lipophilic components are extracted from the precipitate using organic solvents. This targeted extraction approach maximizes the concentration of each component class.

Inventive Principle:
Principle #2Taking out (Extraction)

2Reliability

If multiple extraction stages are implemented to concentrate bioactive components, then the concentration and efficacy of extracts improve, but the extraction time and process duration increase

Engineering Contradiction:
Improveefficacy of extractVSAvoidextraction process duration
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The extraction process maintains continuous productive action through optimized sequential steps. Cell disruption is immediately followed by centrifugation, then size exclusion chromatography, and finally ultrafiltration, with each step building upon the previous one. This continuous multi-stage approach efficiently concentrates bioactive components without unnecessary interruptions, achieving high efficacy while controlling process duration.

Inventive Principle:
Principle #20Continuity of useful action

3Adaptability or versatility

If conventional extraction is used, then the process is simple and quick, but the antioxidant, anti-inflammatory, and antitumor properties are not fully utilized

Engineering Contradiction:
Improvepharmaceutical and nutritional applicationsVSAvoidextraction and purification system
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The extracted bioactive components are demonstrated to possess multiple functions: antioxidant activity (scavenging free radicals), anti-inflammatory effects (inhibiting cyclooxygenase-2), and antitumor properties (inhibiting cell proliferation). The patent shows these components can be applied across diverse fields including pharmaceuticals, nutraceuticals, and cosmetics, making the extraction system universally valuable despite its complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process yields extracts with significantly increased antioxidant and anti-inflammatory activities, demonstrating potent inhibition of cyclooxygenase-2 enzyme and antiproliferative effects, suitable for prophylaxis or treatment of inflammation and oxidative degeneration, and potential use in dietary supplements, cosmetics, and pharmaceuticals.

Implementation Method 1

centrifuging the product of step a) to separate the supernatant (retaining most of the cytoplasmatic fraction) from the precipitate (retaining most of the cell wall fraction)

Methodology Applied
Scientific EffectCentrifugation: Centrifuge

Implementation Method 2

passing the supernatant through an ultra-filtration membrane. In particular, to prepare extracts concentrated in water-soluble components, the primary aqueous extract described above (Basic Extract) is subjected to size-exclusion ultrafiltration

Methodology Applied
Scientific EffectSize exclusion separation: Molecular Sieve

Implementation Method 3

The lipophilic components of the extract are mainly represented by carotenes, chlorophyll, and alpha-linolenic acid (18:3n-3), all of which are present in relatively high amounts in AFA algae

Methodology Applied
Scientific EffectLiquid-liquid extraction: Liquid-Liquid Extraction

Data Source

PatentEP2032122B1Extracts of aphanizomenon flos aquae (AFA klamath), active compounds, and their uses
Publication Date: 2016.04.13 NUTRATEC SRL
  • EP2032122B1 patent drawingFigure 1
  • EP2032122B1 patent drawingFigure 2
  • EP2032122B1 patent drawingFigure 3

AI summary

The invention provides extracts of the microalga Aphanizomenon Flos Aquae Aquae Ralfs ex Born. & Flah. Var. flos aquae (AFA Klamath) and biologically active components thereof, in particular AFA-phycocyanins, determined as the complex c-phycopcyanin/phycoerythrocyanin (including the chromophore phycoviolobilin), AFA-phytochrome and mycosporine-like aminoacids (MAAs), nutritional, cosmetic and pharmaceutical compositions containing the same, for use in the prophylaxis or treatment of diseases, disturbances or conditions involving acute or chronic inflammation and oxidative degeneration of body cells or tissues or uncontrolled cell proliferation.