Ag Alloy Sputtering Target for Ion Migration Resistance

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Miniaturization of electrode and wiring patterns in displays, LEDs, and touch panels leads to increased susceptibility to short-circuiting due to ion migration, necessitating a Ag alloy film with improved environmental and ion migration resistance.

Innovation Solution

A Ag alloy sputtering target with a composition including Cu, Sn, Sb, Mg, In, and Ti in specific atomic percentage ranges, along with sulfur to form silver sulfide, enhancing film wettability and ion migration resistance, while controlling impurity levels to prevent agglomeration and abnormal electrical discharge.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If Ag film is used for conductive patterns, then electrical conductivity is improved, but ion migration resistance deteriorates leading to short-circuiting in miniaturized patterns

Engineering Contradiction:
Improveion migration resistanceVSAvoidshort-circuiting
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent uses composite materials by combining Ag with alloying elements (Cu, Sn, Sb, Mg, In, Ti) to create an Ag alloy film that maintains electrical conductivity while improving ion migration resistance. The composite structure prevents Ag ion migration through the alloying elements that form barriers to ion movement.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the compositional parameters of the Ag film by controlling the content of alloying elements within specific ranges (e.g., Cu: 0.1-10.0 at%, Sn: 0.1-5.0 at%, Sb: 0.1-2.0 at%). These parameter changes optimize both electrical conductivity and ion migration resistance without causing short-circuiting.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If alloying elements are added to improve ion migration resistance, then reliability is improved, but film wettability and agglomeration control become problematic

Engineering Contradiction:
Improveion migration resistanceVSAvoidfilm wettability and agglomeration
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent precisely controls the compositional parameters of multiple alloying elements simultaneously (Cu: 0.1-10.0 at%, Sn: 0.1-5.0 at%, Sb: 0.1-2.0 at%, Mg: 0.1-1.0 at%, In: 0.1-0.5 at%, Ti: 0.1-0.5 at%) to achieve optimal balance between ion migration resistance and film wettability. This multi-parameter optimization prevents agglomeration while maintaining reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a multi-element composite alloy system where different elements work synergistically: Cu and Sn improve wettability, while Sb, Mg, In, and Ti contribute to ion migration resistance. The composite nature of the alloy allows simultaneous optimization of multiple properties that would be conflicting in single-element additions.

Inventive Principle:
Principle #40Composite materials

3Reliability

If S is added to form silver sulfide for improving ion migration resistance, then reliability is improved, but manufacturing precision becomes challenging due to impurity control

Engineering Contradiction:
Improveion migration resistanceVSAvoidimpurity control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the sulfur content parameter to a very specific range (0.5-200 atppm) to form sufficient silver sulfide for ion migration resistance while maintaining manufacturing precision. This precise parameter control allows the formation of protective sulfide layers without excessive impurity accumulation that would degrade film quality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by concentrating sulfur at the film surface to form silver sulfide layers where they are most effective for preventing ion migration. The sulfur is not uniformly distributed throughout the bulk but is localized at the surface interface, maximizing its protective effect while minimizing overall impurity content and maintaining manufacturing precision.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The Ag alloy film exhibits excellent heat-moisture resistance and ion migration resistance, effectively preventing short-circuiting in miniaturized patterns and maintaining high electrical conductivity.

Implementation Method 1

a Ag alloy sputtering target... used during depositing a Ag alloy film

Methodology Applied
Scientific EffectSputtering: Sputtering

Implementation Method 2

since the Ag alloy sputtering target of the present invention includes S in a range of 0.5 atomic ppm or more and 200 atomic ppm or less, silver sulfide is formed on the surface of the deposited Ag alloy film

Methodology Applied
Scientific EffectSilver sulfide formation: Chemical Bonding

Data Source

PatentUS10577687B2Ag alloy sputtering target and Ag alloy film manufacturing method
Publication Date: 2020.03.03 MITSUBISHI MATERIALS CORP
  • US10577687B2 patent drawing

AI summary

A sputtering target, which has a composition comprising: one or more elements selected from Cu, Sn, Sb, Mg, In, and Ti in a range of 0.1 atomic % or more and 15.0 atomic % or less in total; S in a range of 0.5 atomic ppm or more and 200 atomic ppm or less; and a Ag balance including inevitable impurities, is provided.