Ag-Based Oxide Contact Material with Oriented Particles

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing methods for preparing Ag-based oxide contact materials with small reinforcing particles often result in poor dispersivity, leading to increased electrical resistance, reduced ductility, and processing difficulties, while also compromising arc ablation resistance and electrical conductivity.

Innovation Solution

A method involving chemical co-precipitation followed by high energy ball milling, sieving, and directional hot extrusion to achieve evenly dispersed and directionally arranged reinforcing particles within the Ag matrix, enhancing particle connectivity and forming a fiber-like structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If chemical co-precipitation method is used to prepare composite powder, then reinforcing particles can be dispersedly distributed in Ag matrix, but electrical resistance is greatly increased due to electron scattering effect

Engineering Contradiction:
Improvedispersivity of reinforcing particlesVSAvoidelectrical conductivity
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent applies local quality by creating two distinct particle distribution zones: dispersed fine particles for arc ablation resistance and directionally arranged elongated particles for electrical conductivity. The directional arrangement along the extrusion direction ensures electron transport pathways are maintained, while the dispersed fine particles provide local protection against arc erosion without causing excessive electron scattering.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent transitions from isotropic particle distribution to anisotropic directional arrangement through hot extrusion. The elongated particles are oriented along the extrusion direction, creating a dimensionally structured distribution that simultaneously achieves good electrical conductivity along the orientation direction and uniform arc ablation resistance across the contact surface.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Strength

If reinforcing particles are dispersively distributed to improve intensity and hardness, then resistance to mechanical wear is improved, but elongation is greatly decreased resulting in poor ductility

Engineering Contradiction:
Improveresistance to mechanical wearVSAvoidductility
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent applies local quality by creating two distinct particle distribution zones: dispersed fine particles for arc ablation resistance and directionally arranged elongated particles for electrical conductivity. The directional arrangement along the extrusion direction ensures electron transport pathways are maintained, while the dispersed fine particles provide local protection against arc erosion without causing excessive electron scattering.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining Ag matrix with dual-phase oxide particles (fine dispersed particles and elongated directionally arranged particles). This composite structure integrates the benefits of both particle distributions: the fine particles provide wear resistance while the elongated particles maintain ductility through their orientation that facilitates plastic deformation.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If conventional powder metallurgy sintering method is used, then processing is relatively simple, but reinforced particles cluster and cannot be dispersively distributed

Engineering Contradiction:
Improvesimplicity of processingVSAvoiddispersivity of reinforcing particles
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent applies preliminary action by pre-forming composite powder with controlled particle distribution through chemical co-precipitation and high-energy ball milling before sintering. This preliminary preparation ensures that the oxide particles are uniformly dispersed and properly sized before the sintering process, preventing clustering during subsequent processing steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses high-energy ball milling, which involves intense mechanical vibration and impact, to disperse oxide particles uniformly throughout the Ag matrix. The mechanical energy from ball milling breaks up particle clusters and ensures homogeneous distribution, which is then maintained during the subsequent hot extrusion process.

Inventive Principle:
Principle #18Mechanical vibration

4Strength

If small nanoscale oxide particles are dispersively distributed, then contact area between particles and Ag matrix is increased, but electrical resistance is greatly increased affecting product performance

Engineering Contradiction:
Improveintensity and hardnessVSAvoidelectrical conductivity
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies segmentation by dividing the oxide particle population into two distinct size and shape categories: fine particles for wear resistance and elongated particles for conductivity. This segmentation allows each particle type to fulfill its specific function without the negative effects of the other, resolving the contradiction between mechanical strength and electrical conductivity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies local quality by creating two distinct particle distribution zones: dispersed fine particles for arc ablation resistance and directionally arranged elongated particles for electrical conductivity. The directional arrangement along the extrusion direction ensures electron transport pathways are maintained, while the dispersed fine particles provide local protection against arc erosion without causing excessive electron scattering.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method significantly improves arc ablation resistance by 10-20%, electrical conductivity by 5-15%, resistance to welding by 10-20%, and durability by 10-30%, while simplifying the production process and improving material processability.

Implementation Method 1

preparing precipitate of Ag + and oxide particles by chemical co-precipitation method

Methodology Applied
Scientific EffectChemical co-precipitation: Coprecipitation

Implementation Method 2

granulating the composite powders by high energy ball milling

Methodology Applied
Scientific EffectMechanical granulation:

Implementation Method 3

mixing the granulated powders and Ag matrix, and processing the mixed powder by hot extrusion

Methodology Applied
Scientific EffectHot extrusion: Extrusion

Implementation Method 4

processing the mixed powder by hot extrusion

Methodology Applied
Scientific EffectThermal energy: Heating

Data Source

PatentEP2538423B1Method for preparing silver-based oxide electrical contact material with oriented particles
Publication Date: 2018.03.28 WENZHOU HONGFENG ELECTRICAL ALLOY

AI summary

In the present invention, a method of preparing Ag-based oxide contact materials with directionally arranged reinforcing particles is disclosed, comprising steps of: a) preparing evenly dispersed composite powders by chemical co-precipitation method combining with roasting, b) granulating the composite powders by high energy ball milling, and sieving the powders, c) mixing the powders and Ag matrix in a powder mixing machine, d) cold isostatic pressing, e) sintering, f) hot-pressing, g) hot-extruding to obtain Ag-based oxide contact materials with directionally arranged reinforcing particles. This method can obtain particle reinforced Ag-based material with good electrical performance even when the reinforced (oxide) particles are very small. This method is simple, easy to operate, and does not require special equipment. The resistance to welding and arc erosion, electric conductivity and the processability of the material prepared through this present invention can be greatly improved.