AGM Battery Negative Active Material for Charge Acceptance

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Solution Overview

Problem

Existing lead-acid batteries, particularly AGM batteries, face challenges in providing consistent and reliable performance, especially in supporting additional loads and maintaining optimal performance during stop events in start-stop vehicles.

Innovation Solution

The development of a lead-acid storage battery with improved performance, featuring positive and negative plates with specific grid structures, electrochemically active materials including barium sulfate and expanders, and an absorbent glass mat separator, along with an optimized sulfuric acid electrolyte solution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional AGM battery structure is used, then basic starting function is provided, but charge acceptance and cycling performance are insufficient

Engineering Contradiction:
Improvecharge acceptanceVSAvoidcycling performance
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent modifies the chemical composition parameters of the negative electrochemically active material by incorporating barium sulfate and specific expanders, changing the material properties to improve both charge acceptance and cycling performance simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite negative active material comprising barium sulfate, expander, and lead compounds, creating a multi-component material system that achieves superior charge acceptance (up to 5 times better) and extended cycling life compared to traditional single-material compositions

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If battery supports additional prolonged loads for vehicle electronics, then electrical load capacity increases, but battery reliability during stop events deteriorates

Engineering Contradiction:
Improveelectrical load capacityVSAvoidperformance consistency
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent applies different material compositions to different electrodes, with the negative electrode receiving special treatment through barium sulfate and expander addition, creating localized optimization that enables high load capacity while maintaining overall battery reliability

Inventive Principle:
Principle #3Local quality

3Speed

If fast rechargeability is optimized, then charge acceptance improves, but manufacturing complexity increases

Engineering Contradiction:
ImproverechargeabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The patent changes the chemical parameters of the negative active material (adding barium sulfate and expander) to inherently improve charge acceptance speed, achieving fast rechargeability through material composition rather than complex structural modifications

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances charge acceptance, cycling performance, and rechargeability, providing up to 5 times better dynamic charge acceptance compared to existing AGM batteries, while maintaining cold cranking capacity and extended service life.

Implementation Method 1

an absorbent glass mat separator between the positive plate and the negative plate

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

The lead, lead dioxide and electrolyte provide a chemical means of storing electrical energy which can perform useful work when the terminals of a battery are connected to an external circuit

Methodology Applied
Scientific EffectElectrochemical reaction: Redox Reactions

Implementation Method 3

the negative electrochemically active material comprises, in part, barium sulfate and an expander

Methodology Applied
Scientific EffectElectrochemical reaction: Redox Reactions

Data Source

PatentUS12288897B2Absorbent glass mat battery
Publication Date: 2025.04.29 CLARIOS GERMANY GMBH & CO KG
  • US12288897B2 patent drawing
  • US12288897B2 patent drawing
  • US12288897B2 patent drawing

AI summary

A lead-acid battery is disclosed. The lead-acid storage battery has a container with a cover, the container including one or more compartments. One or more cell elements are provided in the one or more compartments. The one or more cell elements include a positive plate, the positive plate having a positive grid and a positive electrochemically active material on the positive grid; a negative plate, the negative plate having a negative grid and a negative electrochemically active material on the negative grid, wherein the negative electrochemically active material comprises barium sulfate and an organic expander; and a separator between the positive plate and the negative plate. Electrolyte is provided within the container. One or more terminal posts extend from the cover and are electrically coupled to the one or more cell elements.