Air Battery pH Detection for Water Ingress Monitoring

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Solution Overview

Problem

Conventional air batteries face difficulties in quickly detecting the ingress of water, which can lead to deterioration, as the operating voltage remains unchanged even when water enters the battery.

Innovation Solution

Incorporating a pH-detecting means, such as a pH indicator mixed in the electrolyte layer and a window for visual observation, along with an output means for electronic signals when the pH value exceeds a threshold, allows for rapid detection of water entry by monitoring pH variations attributed to the reaction of alkali metals with water.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If voltage detection is used to monitor battery status, then the monitoring system is simple, but water ingress cannot be detected quickly because operating voltage does not change when water enters

Engineering Contradiction:
Improvemonitoring system complexityVSAvoidwater ingress detection capability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent changes the detection parameter from voltage to pH value. When water enters the battery, it reacts with the alkali metal anode to produce hydroxide ions, changing the pH of the electrolyte. The pH-detecting means detects this pH change to indicate water ingress, resolving the limitation of voltage detection which shows no change during water contamination.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a pH-detecting means is added to detect water ingress, then detection capability is improved, but device complexity increases

Engineering Contradiction:
Improvewater ingress detection capabilityVSAvoidbattery structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent introduces a pH-detecting means as an intermediary indicator system. This detector acts as a mediator between the chemical reaction (water + alkali metal → hydroxide) and the user, providing visual or electrical signal output when pH changes occur, thereby enabling indirect but reliable detection of water ingress without requiring direct sensing of the reaction itself.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs pH indicators that undergo color changes in response to pH variations in the electrolyte. When water enters and reacts with the alkali metal anode, the resulting pH change causes the indicator to change color, providing a simple visual detection method that minimizes system complexity while improving reliability.

Inventive Principle:
Principle #32Color changes

3Speed

If pH indicator is mixed in the electrolyte layer, then detection response is faster, but manufacturing precision requirements increase

Engineering Contradiction:
Improvedetection response speedVSAvoidelectrolyte layer uniformity
Core Design Contradiction:
SpeedVSManufacturing precision

Solution Approach 1:

The patent merges the pH indicator directly into the electrolyte layer, combining two previously separate components (electrolyte and indicator) into a single integrated medium. This allows the indicator to be uniformly distributed throughout the electrolyte, ensuring rapid and comprehensive detection of pH changes anywhere in the battery, thereby improving detection speed while the merging process itself helps maintain uniformity.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enables quick detection of water ingress, thereby preventing battery deterioration and facilitating early intervention to prevent abnormality or runaway conditions.

Implementation Method 1

a pH-detecting means being provided inside the housing

Methodology Applied
Scientific EffectpH detection:

Implementation Method 2

detect pH variation attributed to an alkaline substance produced by reaction of an alkali metal and water entered into the housing

Methodology Applied
Scientific EffectChemical reaction between alkali metal and water producing alkaline substance: Chemical Bonding

Implementation Method 3

the pH-detecting means contains a pH indicator

Methodology Applied
Scientific EffectpH indicator color change:

Data Source

PatentUS8859152B2Air battery
Publication Date: 2014.10.14 TOYOTA JIDOSHA KK
  • US8859152B2 patent drawing
  • US8859152B2 patent drawing
  • US8859152B2 patent drawing

AI summary

An air battery which is capable of detecting entering of water quickly. The air battery includes: a power section which includes an air electrode, an anode containing an alkali metal, and an electrolyte layer containing an electrolyte for conducting ion between the air electrode and the anode; and a housing configured to receive the power section, a pH-detecting means being provided inside the housing.