Method for producing one or more air products and air separation system

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Solution Overview

Problem

Conventional air separation plants face challenges in achieving flexible and rapid load changes, leading to imbalances in cryogenic liquid distribution and deteriorating product purity during transitions in production volume.

Innovation Solution

Implementing a delayed or leading setpoint adjustment of fluid streams in the rectification column system, particularly the nitrogen-rich liquid reflux, to synchronize with changes in total air quantity processed, allowing for smoother load changes without compromising product purity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If rapid load changes are implemented in air separation plants, then flexibility and productivity are improved, but product purity deteriorates due to imbalances in cryogenic liquid distribution

Engineering Contradiction:
Improveload change speedVSAvoidproduct purity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The control system performs preliminary actions by adjusting the nitrogen-rich liquid reflux quantity in advance before the actual load change occurs. When a load increase is detected, the system increases the reflux quantity beforehand to prevent purity deterioration. This proactive adjustment ensures that the rectification columns maintain proper liquid distribution even during rapid load changes, thereby preserving product purity while enabling flexible productivity changes.

Inventive Principle:
Principle #10Preliminary action

2Stability of the object's composition

If conventional control methods are used during load changes, then system stability is maintained, but flexibility and rapid load changes are limited

Engineering Contradiction:
Improvesystem stabilityVSAvoidload change flexibility
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The control system dynamically adapts the nitrogen-rich liquid reflux quantity based on real-time load conditions. Rather than using fixed conventional control parameters, the system continuously adjusts the reflux flow rate in response to load changes. This dynamic control approach allows the plant to rapidly transition between load conditions while maintaining system stability through active compensation of cryogenic liquid distribution imbalances.

Inventive Principle:
Principle #15Dynamics

3Manufacturing precision

If backup storage facilities with higher capacities are provided to support load changes, then product purity is maintained, but construction costs increase

Engineering Contradiction:
Improveproduct purityVSAvoidconstruction costs
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The control system enables the air separation plant to self-regulate during load changes by automatically adjusting the nitrogen-rich liquid reflux quantity. This self-service capability eliminates the need for large backup storage facilities, as the control system itself provides the necessary compensation for load transitions. The plant uses its own internal resources (reflux control) rather than requiring external backup infrastructure, thereby reducing construction costs while maintaining product purity.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables flexible and rapid load changes with minimal impact on product purity, reducing the need for backup storage and potentially lowering construction and operating costs.

Implementation Method 1

The production of air products in liquid or gaseous state by cryogenic separation of air in air separation plants is known and described

Methodology Applied
Scientific EffectCryogenic rectification: Distillation

Implementation Method 2

The rectification columns of the aforementioned rectification column systems are operated at different pressure levels

Methodology Applied
Scientific EffectPressure level differentiation: Pressure Gradient

Implementation Method 3

heat exchanger for cooling and heating of gas streams in counter-current heat exchange

Methodology Applied
Scientific EffectCounter-current heat exchange: Heat Exchanger

Implementation Method 4

a main condenser for condensing a gaseous, nitrogen-rich overhead product of the high-pressure column

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 5

an evaporator for evaporating a liquid oxygen product

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 6

compressed air in an adjustable total air quantity

Methodology Applied
Scientific EffectCompression: Compression

Data Source

PatentEP3864357B1Method for producing one or more air products and air separation system
Publication Date: 2025.07.23 LINDE AG
  • EP3864357B1 patent drawingFigure 1
  • EP3864357B1 patent drawingFigure 2
  • EP3864357B1 patent drawingFigure 3

AI summary

The invention relates to a method for obtaining one or more air products, wherein an air separation system (100) having a rectification column system (10) is used, in which pressurised air is processed in an adjustable total air volume, wherein the total air volume is set to a first value during a first operating period (T1) and set to a second value that is different from the first value during a second operating period (T2), and wherein the setting of the total air volume is changed from the first value to the second value in a third operating period (T3) from a first time (X1) to a second time (X2). The second operating period (T2) is after the first operating period (T1), the third operating period (T3) is between the first operating period (T1) and the second operating period (T2). According to the invention, in the third operating period (T3), a setting of a volume of a fluid, which is formed via rectification using the pressurised air and transported in or out of the rectification column system (10), is changed from a third time (X3) up to a fourth time (X4), wherein the third time (X3) is before or after the first time (X1) and before the second time (X2), and the fourth time (X4) is after the first time (X1) and the third time (X3) and before or after the second time (X2). A time period between the first time (X1) and the second time (X2) is set to be substantially the same as a time period between the third time (X3) and the fourth time (X4). The invention also relates to a corresponding air separation system (100).