Al Conductive Line Stack for Residue-Free Display Etching

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Solution Overview

Problem

The generation of excessive residue during the etching process of conductive lines in display devices, particularly when using aluminum (Al) materials, which hinders the production of high-resolution displays with low resistance conductive lines.

Innovation Solution

A conductive line structure comprising a first layer of aluminum or aluminum alloy, a second layer of refractory metal nitride, and a third layer with a multilayer structure of refractory metals, including titanium, to prevent residue formation during etching, achieved through discontinuous deposition techniques.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a capping layer including titanium is formed on the aluminum conductive line to prevent hillock generation, then hillock formation is prevented, but excessive residue is generated during the etching process

Engineering Contradiction:
Improvehillock preventionVSAvoidresidue generation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The capping layer is divided into multiple sub-layers (first capping sub-layer, second capping sub-layer, and third capping sub-layer) with different materials and functions. The first sub-layer (titanium) prevents hillock formation, the second sub-layer (titanium nitride) provides etch selectivity to reduce residue, and the third sub-layer (titanium oxide) offers additional protection and adhesion. This segmentation resolves the contradiction by distributing functions across multiple layers rather than relying on a single thick layer.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The capping layer uses a composite structure combining different refractory materials (titanium, titanium nitride, and titanium oxide) with complementary properties. Each material contributes specific characteristics: titanium for hillock prevention, titanium nitride for etch resistance, and titanium oxide for adhesion and protection. This composite approach allows simultaneous achievement of hillock prevention and residue reduction.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the thickness of the capping layer is increased to improve hillock prevention, then hillock formation is reduced, but excessive residue is generated during etching

Engineering Contradiction:
Improvehillock preventionVSAvoidetching precision
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

Instead of using a single thick capping layer, the structure segments the total thickness into multiple thinner sub-layers with specific functions. The first sub-layer (50-150 nm titanium) provides sufficient hillock prevention, while the second sub-layer (50-150 nm titanium nitride) and third sub-layer (10-50 nm titanium oxide) control etching behavior and reduce residue generation through their material properties rather than relying on increased total thickness.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the material composition parameters of each sub-layer to optimize both hillock prevention and etching performance. By selecting specific materials with different etch rates and properties (titanium, titanium nitride, titanium oxide), the structure achieves effective hillock prevention at controlled thicknesses while maintaining etching precision through material selection rather than thickness alone.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This structure effectively reduces residue generation during etching, enabling the production of high-resolution display devices with improved conductive line performance and reduced hillock formation.

Implementation Method 1

a third layer disposed on the second layer, the third layer including a refractory metal having a multilayer structure including a plurality of stacked sub-layers

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS11871628B2Method of manufacturing conductive line for display device including the same
Publication Date: 2024.01.09 SAMSUNG DISPLAY CO LTD
  • US11871628B2 patent drawing
  • US11871628B2 patent drawing
  • US11871628B2 patent drawing

AI summary

A conductive line for a display device may include a first layer including aluminum (Al) or an aluminum alloy, a second layer disposed on the first layer, the second layer including titanium nitride (TiNx), and a third layer disposed on the second layer, the third layer including titanium (Ti) and having a multilayer structure including a plurality of stacked sub-layers.