Al-Mg Alloy Metallized Film Capacitor Moisture Resistance

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Solution Overview

Problem

Conventional metallized film capacitors used in hybrid electric vehicles face challenges with high moisture resistance and leak current issues, particularly under high-temperature and high-humidity conditions, which affect their performance and reliability.

Innovation Solution

The use of metal vapor-deposition electrodes made of an alloy containing aluminum and magnesium, which reacts with moisture to reduce leak current and improve moisture resistance, along with specific distribution and concentration of magnesium to enhance the capacitor's performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional metal vapor-deposition electrodes are used, then the capacitor structure is simple and manufacturing is easy, but moisture resistance is poor and leak current increases under high-temperature and high-humidity conditions

Engineering Contradiction:
Improvemoisture resistanceVSAvoidelectrode composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining aluminum and magnesium in the vapor-deposition electrode to create an Al-Mg alloy. This composite electrode structure provides both the electrical conductivity needed for capacitor function and the moisture-resistant properties of magnesium, which forms a protective oxide layer that prevents moisture penetration and reduces leak current under high-temperature and high-humidity conditions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the compositional parameters of the electrode by incorporating magnesium at specific concentrations (0.1-10 at%). This parameter change transforms the electrode from a simple metal structure to one with controlled chemical composition that actively resists moisture through the formation of magnesium oxide, thereby improving reliability without excessive complexity.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If aluminum-only vapor-deposition electrodes are used, then manufacturing precision is easier to control, but leak current increases due to poor moisture resistance

Engineering Contradiction:
Improveleak current reductionVSAvoidelectrode composition control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by precisely controlling the magnesium content in the Al-Mg alloy electrode within the range of 0.1-10 at%. This controlled compositional parameter ensures that enough magnesium is present to form a protective oxide layer for moisture resistance and leak current reduction, while maintaining the electrode's electrical properties and manufacturability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by having magnesium distributed throughout the electrode structure to locally form protective oxide layers at moisture contact points. This localized protection mechanism reduces leak current at critical interfaces without requiring the entire electrode structure to be fundamentally redesigned, thus balancing manufacturing precision with reliability improvement.

Inventive Principle:
Principle #3Local quality

3Volume of stationary object

If the capacitor is designed for small size and light weight, then volume is reduced, but moisture resistance becomes more difficult to maintain under harsh conditions

Engineering Contradiction:
Improvecapacitor volumeVSAvoidmoisture resistance
Core Design Contradiction:
Volume of stationary objectVSReliability

Solution Approach 1:

The patent applies composite materials in the electrode to achieve a high-performance-to-size ratio. The Al-Mg alloy provides enhanced moisture resistance in a thin-film format, allowing the capacitor to maintain small volume while achieving superior reliability. The magnesium component creates a protective barrier that is effective even in compact structures where surface area to volume ratio is high.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies self-service through the self-healing property of the magnesium oxide layer. When moisture penetrates or defects occur, the magnesium continuously forms protective oxide that seals and repairs the electrode structure automatically. This self-service mechanism maintains moisture resistance in small-capacitor designs without requiring additional protective structures or increased size.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The metallized film capacitor with aluminum-magnesium electrodes exhibits superior moisture-resistant properties, reducing leak current and maintaining capacitance stability even under harsh conditions, thus providing improved reliability and performance.

Implementation Method 1

metal vapor-deposition electrodes made of an alloy containing aluminum and magnesium, which reacts with moisture to reduce leak current and improve moisture resistance

Methodology Applied
Scientific EffectChemical reaction with moisture: Redox Reactions

Implementation Method 2

metal vapor-deposition electrode formed on a dielectric film by vapor-depositing metal

Methodology Applied
Scientific EffectVapor deposition: Physical Vapour Deposition

Data Source

PatentEP2458602B1Metallized film capacitor and case mold type capacitor including same
Publication Date: 2017.09.27 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • EP2458602B1 patent drawingFigure 1
  • EP2458602B1 patent drawingFigure 2
  • EP2458602B1 patent drawingFigure 3

AI summary

A metallized film capacitor includes two metallized films. Each metallized film includes a dielectric film and a metal vapor-deposition electrode provided on an upper surface of the dielectric film. A metal vapor-deposition electrode of at least one of the first metal vapor-deposition electrode and the second metal vapor-deposition electrode is made of substantially only aluminum and magnesium. This metallized film capacitor has superior leak current characteristics and moisture resistant performances, and can be used for forming a case mold type capacitor with a small size.