Al-Sb-Te Phase Change Material for High-Speed Memory

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Solution Overview

Problem

Current phase change materials like Ge2Sb2Te2 face limitations in write and erase speed, reliability, and thermal stability, making them unsuitable for high-temperature applications and limiting their potential as next-generation memory technology.

Innovation Solution

A phase change material composed of a mixture of aluminum (Al), antimony (Sb), and tellurium (Te) with a general formula Alx(SbyTe1-x), which exhibits high crystallization speed, thermal stability, and low power consumption, and is fabricated using methods like physical vapor deposition, enabling reversible resistivity changes for data storage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If Ge2Sb2Te2 phase change material is used, then data storage function is achieved, but crystallization speed is slow (hundreds of ns) and thermal stability is poor

Engineering Contradiction:
Improvecrystallization speedVSAvoidthermal stability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of the phase change material by incorporating Al, Sb, and Te elements in specific ratios (AlxSbyTe1-x-y) to achieve optimal crystallization speed and thermal stability. This compositional parameter optimization resolves the contradiction between fast crystallization and thermal stability by finding the right balance of elements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite phase change material system combining multiple elements (Al, Sb, Te) with complementary properties. Al contributes to thermal stability, Sb provides phase change characteristics, and Te enhances crystallization speed. The synergistic combination of these elements in a composite material resolves the contradiction between individual material limitations.

Inventive Principle:
Principle #40Composite materials

2Productivity

If Ge2Sb2Te2 phase change material is used, then phase change memory function is achieved, but write and erase speed is limited

Engineering Contradiction:
Improvewrite and erase speedVSAvoidphase change time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent optimizes the compositional parameters (x, y values in AlxSbyTe1-x-y) to reduce phase change time and increase write/erase speed. By adjusting the Al content and Sb-Te ratio, the material achieves faster crystallization and amorphization rates, directly improving productivity while reducing the time loss during phase transitions.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If Ge2Sb2Te2 phase change material is used, then memory storage is achieved, but power consumption is high

Engineering Contradiction:
Improvedata retentionVSAvoidpower consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent modifies the material composition parameters to achieve a balance between data retention reliability and power consumption. The optimized Al-Sb-Te ratio enables phase change transitions at lower energy thresholds while maintaining stable data retention, thus reducing power consumption without sacrificing reliability.

Inventive Principle:
Principle #35Parameter changes

4Adaptability or versatility

If Ge2Sb2Te2 phase change material is used, then phase change memory function is achieved, but compatibility with CMOS process is poor

Engineering Contradiction:
ImproveCMOS compatibilityVSAvoidfabrication difficulty
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The patent adjusts the compositional parameters of the phase change material to improve compatibility with standard CMOS fabrication processes. By optimizing the Al-Sb-Te ratio and controlling deposition parameters during magnetron sputtering, the material can be integrated into existing CMOS manufacturing lines without requiring specialized process equipment or conditions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The Al-Sb-Te phase change material demonstrates enhanced crystallization speed, thermal stability, and data retention, facilitating efficient data storage and operation under high temperatures, while being compatible with CMOS processes.

Implementation Method 1

Data storage of chalcogenide random access memory is realized by the reversible phase change between amorphous and polycrystalline states when phase change material is activated by applying energy

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

preparing phase change material of Alx(SbyTe1)1-x by magnetron sputtering

Methodology Applied
Scientific EffectMagnetron sputtering: Sputtering

Implementation Method 3

reversible change in resistivity of said phase change material is achieved by employing electrical pulse

Methodology Applied
Scientific EffectResistivity change: Electrical Resistance

Data Source

PatentUS8920684B2Al-Sb-Te phase change material used for phase change memory and fabrication method thereof
Publication Date: 2014.12.30 SHANGHAI INST OF MICROSYSTEM & INFORMATION TECH CHINESE ACAD OF SCI
  • US8920684B2 patent drawing
  • US8920684B2 patent drawing

AI summary

The present invention discloses an Al—Sb—Te phase change material used for PCM and fabrication method thereof. Said phase change material, which can be prepared by PVD, CVD, ALD, PLD, EBE, and ED, is a mixture of three elements aluminum (Al), antimony (Sb) and tellurium (Te) with a general formula of Alx(SbyTe1)1-x, where 0<x≦0.85, 0.67≦y≦7. Said material is electrically driven from outside. By adjusting the content of three elements in the mixture, storage materials with different crystallization temperatures, melting temperatures and activation energies of crystallization can be achieved. Any two elements of aluminum, antimony and tellurium can be bonded to each other, so the adjustability is very high, maintaining the phase change properties in a wide range. Compared with conventional Ge2Sb2Te5, the materials achieved by properly adjusting the element ratio in Alx(SbyTe1)1-x have higher crystallization temperatures, better thermal stability and data retention, and lower melting temperatures, while at the same time inheriting the fast phase change capability from SbyTe1. Moreover, as a common element used in microelectronics, aluminum (Al) features mature technology and nice compatibility with CMOS.