Al-Si-Fe Coating Cover Layer for Tool Wear Reduction

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Solution Overview

Problem

Aluminium-based coatings for steel sheets or strips face issues such as reduced furnace roller service life, high tool wear, non-uniform surface formation, and welding problems due to reaction with ceramic rollers and abrasive nature during hot-forming and cold-forming processes.

Innovation Solution

A cover layer containing aluminium oxide and/or aluminium hydroxide is applied through plasma oxidation or anodic oxidation, produced in a melting bath with specific Si and Fe content, which acts as a separation layer between the coat and ceramic rollers, reducing wear and abrasion, and is treated with hot water or steam to enhance properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an aluminium-based coat is applied by hot-dipping for corrosion protection, then corrosion resistance is improved, but tool wear and abrasion increase during forming processes

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidtool wear and abrasion
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies a composite coating structure consisting of an aluminium-based coat (Al-Si-Fe alloy) combined with a cover layer containing aluminium oxide and/or aluminium hydroxide. This composite structure provides both corrosion protection from the aluminium-based coat and reduced tool wear from the oxide/hydroxide cover layer, resolving the contradiction between corrosion resistance and tool wear.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The cover layer containing aluminium oxide and/or aluminium hydroxide acts as an intermediary between the aluminium-based coat and the forming tools. This intermediate layer reduces direct contact and abrasion between the metallic coat and tools, thereby reducing tool wear while maintaining the corrosion protection function of the underlying aluminium-based coat.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If an aluminium-based coat is applied by hot-dipping, then corrosion protection is improved, but furnace roller service life is reduced due to reaction with ceramic rollers

Engineering Contradiction:
Improvecorrosion protectionVSAvoidfurnace roller service life
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The cover layer containing aluminium oxide and/or aluminium hydroxide serves as a protective intermediary between the aluminium-based coat and the ceramic furnace rollers. This layer prevents direct chemical reaction between the metallic coating and the ceramic rollers, thereby extending furnace roller service life while maintaining the corrosion protection benefits of the aluminium-based coat.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent converts the potential harmful reaction between aluminium and ceramic rollers into a beneficial oxide layer formation. By controlling oxidation to form a stable aluminium oxide/hydroxide cover layer, the inherently reactive aluminium is transformed into a stable, non-reactive protective layer that prevents further harmful reactions with furnace rollers.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If an aluminium-based coat is applied by hot-dipping, then corrosion resistance is improved, but surface uniformity deteriorates due to non-uniform surface formation

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidsurface uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent optimizes the composition parameters of the aluminium-based coat, specifically controlling the Si content at 8-12 wt.% and Fe content at 1-4 wt.%, to achieve more uniform surface formation during hot-dipping. Additionally, the oxidation process parameters are controlled to form a uniform cover layer of aluminium oxide and/or aluminium hydroxide, thereby improving surface uniformity while maintaining corrosion resistance.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If an aluminium-based coat is applied by hot-dipping, then corrosion protection is improved, but welding quality deteriorates due to welding problems

Engineering Contradiction:
Improvecorrosion protectionVSAvoidwelding quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent creates a coating structure with different local properties: the aluminium-based coat provides corrosion protection, while the cover layer containing aluminium oxide and/or aluminium hydroxide provides improved weldability. This local differentiation allows the coating to exhibit different qualities in different regions, resolving the contradiction between corrosion protection and welding quality.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The cover layer significantly reduces tool wear, maintains surface integrity, prevents welding issues, and enhances corrosion resistance, allowing for improved hot-forming and cold-forming processes with reduced maintenance and increased durability.

Implementation Method 1

the coating is subjected to plasma oxidation and/or a hot water treatment and/or a steam treatment and/or an anodic oxidation, in which the coating is oxidised on the surface with oxides or hydroxides being formed

Methodology Applied
Scientific EffectPlasma oxidation: Plasma Enhanced Chemical Vapour Deposition

Implementation Method 2

the coating is subjected to plasma oxidation and/or a hot water treatment and/or a steam treatment and/or an anodic oxidation, in which the coating is oxidised on the surface with oxides or hydroxides being formed

Methodology Applied
Scientific EffectAnodic oxidation: Anodising

Implementation Method 3

the coating is subjected to plasma oxidation and/or a hot water treatment and/or a steam treatment and/or an anodic oxidation, in which the coating is oxidised on the surface with oxides or hydroxides being formed

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS10876195B2Method for producing press-hardened components consisting of steel sheets or steel strips comprising an aluminium-based coating, and pressed-hardened component therefrom
Publication Date: 2020.12.29 SALZGITTER FLASHSTAHL GMBH
  • US10876195B2 patent drawing
  • US10876195B2 patent drawing
  • US10876195B2 patent drawing

AI summary

In an aluminium-based coating for steel sheets or steel strips, the coating includes an aluminium-based coat applied in a hot-dip coating method, a covering layer containing aluminium oxide and/or hydroxide being arranged on the coat. The covering layer is produced by plasma oxidation and/or hot water treatment at temperatures of at least 90° C., advantageously at least 95° C., and/or steam treatment at temperatures of at least 90° C., advantageously at least 95° C. Alternatively, the covering layer containing aluminium oxide and/or hydroxide can be produced by anodic oxidation, the coat being produced in a molten bath with a Si content of between 8 and 12 wt. %, and an Fe content of between 1 and 4 wt. %, the remainder being aluminium.