Alcohol Distillation with Membrane Separation and Heat Recovery

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Solution Overview

Problem

The existing methods for producing alcohol from a water-alcohol mixture face challenges in achieving high energy efficiency due to the limitations of azeotropic mixtures and partial heat utilization in multiple-effect distillation processes.

Innovation Solution

A method involving a multiple-effect distillation column where vapor from the top is condensed and the condensed liquid is fed to a membrane separation apparatus using pervaporation, optimizing heat utilization and energy efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a liquid recovered from the bottom or middle stage of a distillation column is fed to a membrane separation apparatus, then the separation process can proceed, but the liquid requires re-vaporization which worsens energy efficiency

Engineering Contradiction:
Improveseparation process feasibilityVSAvoidenergy efficiency
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The invention extracts the vapor phase from the distillation column top and directs it to the membrane separation apparatus, leaving the liquid phase in the distillation column. This extraction of the vapor stream enables membrane separation without requiring re-vaporization of liquid, thereby resolving the energy efficiency problem while maintaining separation feasibility

Inventive Principle:
Principle #2Taking out (Extraction)

2Adaptability or versatility

If a gas recovered from the top or middle stage of a distillation column is fed to a membrane separation apparatus, then the multiple-effect method can be applied after partial condensation, but the amount of heat that can be utilized for other distillation is limited

Engineering Contradiction:
Improvemultiple-effect method applicabilityVSAvoidheat utilization amount
Core Design Contradiction:
Adaptability or versatilityVSLoss of energy

Solution Approach 1:

The condensation heat from the vapor stream is utilized for multiple purposes: it provides the driving force for membrane separation through pervaporation and simultaneously serves as heat source for other distillation columns in the multiple-effect system. This multi-functional use of condensation heat maximizes energy utilization while enabling the multiple-effect method

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Adaptability or versatility

If the vapor recovered from the top of a distillation column is partially condensed, then the multiple-effect method can be applied, but adequate effect of the multiple-effect method cannot be obtained

Engineering Contradiction:
Improvemultiple-effect method implementationVSAvoidenergy efficiency
Core Design Contradiction:
Adaptability or versatilityVSLoss of energy

Solution Approach 1:

The invention changes the condensation parameter from partial condensation to total condensation of the vapor stream. This parameter change enables adequate heat utilization for the multiple-effect method while the pervaporation membrane separation handles the liquid phase, achieving both multiple-effect implementation and high energy efficiency

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances overall energy efficiency by fully utilizing the heat of condensation for distillation, improving the separation process and reducing energy consumption.

Implementation Method 1

a concentration step of introducing a water-alcohol mixed solution into a multiple-effect distillation column to concentrate the water-alcohol mixed solution

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

a condensation step of introducing a vapor recovered from the top of the multiple-effect distillation column into a condenser to condense the vapor

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

a separation step of introducing the water-alcohol mixed solution condensed in the condensation step in a liquid phase into a membrane separation apparatus to separate the water and alcohol in the mixed solution

Methodology Applied
Scientific EffectPervaporation: Pervaporation

Data Source

PatentUS11020685B2Method for producing alcohol
Publication Date: 2021.06.01 MITSUBISHI CHEM CORP
  • US11020685B2 patent drawing
  • US11020685B2 patent drawing
  • US11020685B2 patent drawing

AI summary

The object is to provide a method for producing an alcohol by applying a multiple-effect method to improve the energy efficiency of the whole process. The object is achieved by a method for producing an alcohol including a concentration step of introducing a water-alcohol mixed solution into a multiple-effect distillation column for concentrating the same; a condensation step of introducing a vapor recovered from the top of the distillation column into a condenser for condensing the same; and a separation step of introducing the water-alcohol mixed solution condensed in the condensation step in a liquid phase into a membrane separation apparatus for separating the water and alcohol in the mixed solution.