Alcohol-Mediated Esterification Without Corrosive Catalysts

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Solution Overview

Problem

Current esterification methods using carboxylic acids and dialkyl-carbonates are environmentally detrimental due to the use of strong corrosive catalysts, generation of toxic byproducts, and difficulties in downstream processing, particularly with solvents like dimethylformamide.

Innovation Solution

A method involving the reaction of organic acids with dialkyl-carbonates in an alcohol-containing solvent without extrinsic catalysts, where the alcohol mediates the formation of esters, allowing for high conversion rates and easy isolation of esters through fractional distillation or chromatography.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If strong corrosive mineral acids are used as catalysts in Fischer esterification, then the esterification reaction can proceed, but environmental pollution and corrosion issues arise

Engineering Contradiction:
Improveesterification reaction efficiencyVSAvoidenvironmental pollution and corrosion
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces carbonic acid esters (dimethyl carbonate, diethyl carbonate) as intermediary reagents that mediate the esterification reaction between carboxylic acids and alcohols. These intermediaries enable the reaction to proceed without strong corrosive mineral acid catalysts, thus eliminating the harmful effects while maintaining reaction efficiency. The carbonic acid esters act as mild alkylating agents that transfer alkyl groups to the carboxylic acids to form esters.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the reaction parameters by using carbonic acid esters instead of traditional strong acid catalysts. This parameter change transforms the reaction system from one requiring corrosive catalysts to one that operates under milder conditions with CO2 and alcohol as byproducts, thereby resolving the contradiction between reaction efficiency and environmental friendliness.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If dimethylformamide is used as solvent in esterification reactions, then the reaction can proceed, but downstream processing becomes difficult due to high boiling point and decomposition

Engineering Contradiction:
Improvereaction efficiencyVSAvoiddownstream processing difficulty
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent extracts or removes dimethylformamide from the reaction system by using alternative solvents with lower boiling points and better stability. This eliminates the downstream processing difficulties associated with DMF's high boiling point and decomposition, while maintaining reaction efficiency through the use of carbonic acid esters as reagents.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs solvents that are easier to remove and less problematic for downstream processing. By replacing DMF with solvents that have more favorable volatility and stability characteristics, the patent adopts a strategy of using disposable or easily removable solvent systems that simplify purification steps.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Speed

If extrinsic catalysts are used in esterification reactions, then the reaction rate improves, but neutralization steps are required adding complexity

Engineering Contradiction:
Improvereaction rateVSAvoiddownstream processing complexity
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The patent employs carbonic acid esters that inherently facilitate the esterification reaction without requiring external strong acid or base catalysts. The reaction system becomes self-sufficient, using the carbonic acid ester as both reagent and mild catalyst, thereby eliminating the need for downstream neutralization steps and reducing process complexity while maintaining acceptable reaction rates.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach achieves high yields of esters with minimal side products and eliminates the need for neutralization steps, reducing environmental impact and simplifying downstream processing.

Implementation Method 1

reacting in a reaction mixture an organic acid with a dialkyl-carbonate in the presence of an alcohol-containing solvent without an extrinsic catalyst, wherein said alcohol mediates the formation of said esters

Methodology Applied
Scientific EffectEsterification: Chemical Bonding

Implementation Method 2

isolating said esters by at least fractional distillation, chromatography, or both from said reaction mixture

Methodology Applied
Scientific EffectDistillation: Distillation

Data Source

PatentEP2912007B1Alcohol-mediated esterification of carboxylic acids with carbonates
Publication Date: 2019.11.20 ARCHER DANIELS MIDLAND CO
  • EP2912007B1 patent drawingFigure 1~2
  • EP2912007B1 patent drawingFigure 3A~3D
  • EP2912007B1 patent drawingFigure 4A~4E

AI summary

A process for making esters from organic acids by means of reacting a carboxylic acid with dialkylcarbonate in an alcohol-containing solvent without any extrinsic acid or base catalyst is described. A benefit of the preparation process is that it can make the separation and extraction of ester products simpler and more facile vis-a-vis conventional isolation techniques.