ALD Dielectric Gapfill With Inhibitor Plasma for Void-Free Features

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Solution Overview

Problem

Existing substrate processing systems face challenges in achieving void-free fill of high aspect ratio features, as deposition methods like ALD often result in seams or voids at the center of features, which can lead to unintended conductive material filling and short circuits.

Innovation Solution

A method combining atomic layer deposition (ALD) with inhibitor plasma and etching cycles, where inhibitor plasma gas is used to selectively inhibit deposition in upper feature portions, followed by etching to ensure complete fill without voids, utilizing a controller to manage gas delivery and plasma generation for precise control.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If atomic layer deposition (ALD) is used to gapfill high aspect ratio features, then the feature can be filled with dielectric film, but a seam or void remains at the center of the feature

Engineering Contradiction:
Improvefeature fill qualityVSAvoidvoid-free fill
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The gapfill process is divided into multiple sequential ALD cycles with intermediate etching steps. Each ALD cycle deposits a portion of the dielectric film, and the intermediate etching removes excess material from upper portions, preventing void formation and enabling complete feature fill without seams

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The process employs periodic alternation between deposition and etching operations. ALD cycles are performed repeatedly with intermediate etching steps, creating a rhythmic sequence of depositing and removing material that ensures uniform fill while eliminating voids at the feature center

Inventive Principle:
Principle #19Periodic action

2Manufacturing precision

If multiple ALD cycles are performed to fill high aspect ratio features, then more complete fill is achieved, but deposition time increases

Engineering Contradiction:
Improvefeature fill completenessVSAvoiddeposition time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

Excess dielectric material deposited in upper portions of features during ALD cycles is selectively removed through intermediate etching steps. This extraction of unnecessary material prevents the need for excessive deposition cycles, reducing total processing time while maintaining complete feature fill

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The process intentionally deposits more material than immediately needed in each ALD cycle, then removes the excess through intermediate etching. This partial over-deposition followed by selective removal is more efficient than attempting to deposit precisely the required amount, reducing total cycle time

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for void-free gapfill of high aspect ratio features with dielectric film, reducing the risk of short circuits by ensuring uniform deposition and preventing seam formation, thereby enhancing the reliability of subsequent integration steps.

Implementation Method 1

perform atomic layer deposition (ALD) to deposit film in a feature of the substrate

Methodology Applied
Scientific EffectAtomic layer deposition: Chemical Vapour Deposition

Implementation Method 2

supplying an inhibitor plasma gas to the processing chamber and striking plasma in the processing chamber to inhibit deposition in upper portions of the feature

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 3

supplying an etch gas to the processing chamber to etch the film in the feature of the substrate

Methodology Applied
Scientific EffectEtching:

Data Source

PatentUS12049699B2Dielectric gapfill using atomic layer deposition (ALD), inhibitor plasma and etching
Publication Date: 2024.07.30 LAM RES CORP
  • US12049699B2 patent drawing
  • US12049699B2 patent drawing
  • US12049699B2 patent drawing

AI summary

A plasma generating system generates plasma in a processing chamber. A controller is configured to: a) perform atomic layer deposition (ALD) N times to deposit film in a feature of the substrate; b) after performing a) M of the N times, supply an inhibitor plasma gas to the processing chamber and strike plasma in the processing chamber to create a passivated surface more on upper portions of the feature as compared to lower portions of the feature to inhibit the atomic layer deposition in the upper portions of the feature as compared to the lower portions of the feature; c) supply an etch gas to the processing chamber to etch the film more in the upper portions of the feature than in the lower portions in the feature of the substrate following b); and d) repeat a) to c) one or more times to gapfill the feature without voids.