ALD Nanolaminate Encapsulation for OLED Moisture Barrier
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Solution Overview
Problem
Existing thin-film encapsulations for optoelectronic components, such as OLEDs, have low optical transmission for visible light, making them inadequate for protecting sensitive organic materials from moisture and oxygen while maintaining transparency.
Innovation Solution
A thin-film encapsulation with a layer sequence comprising alternating atomic layer deposition (ALD) layers of titanium oxide and lanthanum oxide, optionally combined with additional layers deposited by thermal vapor deposition or plasma-assisted processes, to create a nanolaminate structure that enhances both barrier effectiveness and optical transmission.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If a thin-layer encapsulation is used to protect against moisture and oxygen, then the protection effectiveness is improved, but the optical transmission for visible light deteriorates
Solution Approach 1:
The patent applies composite materials by creating a nanolaminate structure consisting of alternating layers of titanium oxide and lanthanum oxide. This multi-material composite approach allows the encapsulation to simultaneously achieve high barrier properties against moisture and oxygen while maintaining good optical transmission for visible light, resolving the contradiction between protection effectiveness and optical transparency.
Solution Approach 2:
The encapsulation layer is segmented into multiple thin alternating layers of different materials (titanium oxide and lanthanum oxide) rather than using a single homogeneous layer. This segmentation into nanoscale lamellae enables each material to contribute its specific properties - titanium oxide providing barrier function and lanthanum oxide providing optical transparency - thereby resolving the contradiction between protection and transparency.
2Illumination intensity
If the encapsulation layer thickness is reduced to improve optical transmission, then the transparency is improved, but the barrier effectiveness against moisture and oxygen deteriorates
Solution Approach 1:
By using composite nanolaminate structure with alternating titanium oxide and lanthanum oxide layers, the patent achieves high barrier effectiveness despite reduced overall thickness. The composite nature allows light to pass through the transparent lanthanum oxide layers while the titanium oxide layers provide the necessary barrier function, thus resolving the contradiction between thinness for transparency and thickness for barrier effectiveness.
Solution Approach 2:
Different regions of the encapsulation structure are assigned different local qualities - titanium oxide layers are positioned to provide barrier function while lanthanum oxide layers are positioned to provide optical transparency. This local differentiation of material properties within the nanolaminate structure allows the thin encapsulation to simultaneously achieve both transparency and barrier effectiveness.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution achieves a high optical transmission of at least 70% for visible light while maintaining a robust barrier against moisture and oxygen, suitable for flexible substrates and various optoelectronic components like OLEDs and organic photovoltaic cells.
Implementation Method 1
a first ALD layer deposited by means of atomic layer deposition, which consists of titanium oxide, and a second ALD layer deposited by means of atomic layer deposition, consisting of lanthanum oxide
Data Source
Figure 1~2B
Figure 3~4
Figure 5
AI summary
The invention relates to a thin-layer encapsulation (1) for an optoelectronic component. The thin-layer encapsulation (1) comprises a sequence of layers (2) that comprises the following layers: a first ALD layer (3) deposited by means of atomic layer deposition, and a second ALD layer (4) deposited by means of atomic layer deposition. The invention further relates to a method for producing the thin-layer encapsulation and to an optoelectronic component having such a thin-layer encapsulation.