Alginate Membrane Encapsulation via Ionic Crosslinking

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Solution Overview

Problem

Current methods for encapsulating liquids using alginate are not scalable to larger volumes and do not provide a substantially liquid-tight seal, limiting their application in packaging and storage, particularly for water and other liquids, and contribute to environmental pollution due to the use of non-biodegradable materials like plastic.

Innovation Solution

A method involving the creation of a cross-linked alginate membrane using a calcium-rich ion solution to form a water-insoluble, biodegradable or edible encapsulation for liquids, which can be extruded and pinched to create sealed pockets, allowing for the encapsulation of larger volumes with minimal leakage and improved mechanical resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If alginate is used to encapsulate small volumes of liquid in culinary spherification techniques, then encapsulation is achieved, but the method is not scalable to larger volumes

Engineering Contradiction:
Improvevolume of liquid productVSAvoidscalability
Core Design Contradiction:
Volume of moving objectVSProductivity

Solution Approach 1:

The process segments the encapsulation operation into distinct stages: first forming a liquid-tight seal around the product, then filling the sealed membrane with liquid product. This segmentation allows the membrane to be prepared and sealed before filling, enabling scalability to larger volumes without compromising the liquid-tight seal property.

Inventive Principle:
Principle #1Segmentation

2Reliability

If alginate membrane is used for encapsulation, then biodegradability is achieved, but the membrane is water-soluble and cannot provide liquid-tight sealing

Engineering Contradiction:
Improveliquid-tight sealVSAvoidwater solubility
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical parameter of the alginate membrane by introducing cross-links between polymer chains. This cross-linking transformation converts the water-soluble alginate into a water-insoluble gel structure that maintains biodegradability while achieving liquid-tight sealing capability. The cross-linked network prevents water penetration while preserving the biocompatible and biodegradable nature of alginate.

Inventive Principle:
Principle #35Parameter changes

3Strength

If traditional plastic packaging is used, then mechanical resistance is achieved, but environmental pollution increases

Engineering Contradiction:
Improvemechanical resistanceVSAvoidenvironmental pollution
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the physical and chemical parameters of natural alginate through cross-linking to achieve mechanical resistance comparable to plastic packaging. The cross-linked gel structure provides the necessary strength and durability for packaging applications while maintaining biodegradability, thereby eliminating the environmental pollution associated with traditional plastic materials.

Inventive Principle:
Principle #35Parameter changes

4Strength

If alginate is cross-linked to improve mechanical properties, then water insolubility and structural integrity are achieved, but processing complexity increases

Engineering Contradiction:
Improvemechanical integrityVSAvoidprocess complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by preparing the alginate membrane and forming the liquid-tight seal before filling with the liquid product. This sequence allows the cross-linking process to be completed on an empty membrane structure, simplifying the overall process. The membrane is cross-linked to achieve mechanical integrity and water insolubility prior to product insertion, avoiding the complexity of simultaneous cross-linking and filling.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the encapsulation of larger volumes of liquids with a substantially liquid-tight seal, providing a cost-effective, environmentally friendly alternative to traditional packaging materials, reducing waste and marine pollution, while maintaining biodegradability and mechanical integrity.

Implementation Method 1

applying a calcium rich ion solution to crosslink the membrane and create a water insoluble membrane

Methodology Applied
Scientific EffectIonic bonding: Chemical Bonding

Implementation Method 2

The method enables the encapsulation of larger volumes of liquids with a substantially liquid-tight seal

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Data Source

PatentEP3601061B1Method of encapsulating liquid products
Publication Date: 2023.03.08 SKIPPING ROCKS LAB LTD
  • EP3601061B1 patent drawingFigure 1~2
  • EP3601061B1 patent drawingFigure 3~8
  • EP3601061B1 patent drawingFigure 9~11

AI summary

The invention relates to a method for encapsulating a liquid product, the method comprising blending together a solution of alginate and a thickener and extruding through an appropriately shaped die to form a membrane, applying a calcium rich ion solution to crosslink the membrane and create a water insoluble membrane, filling the water insoluble membrane with the liquid product; and sealing the membrane around the liquid product, encapsulating the liquid product therein.