Aligned Carbon Nanotube Composite Reinforcement

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Solution Overview

Problem

Existing methods for processing carbon nanotubes in composite materials face challenges such as poor alignment, agglomeration, and dispersion, leading to materials with inadequate mechanical, thermal, and electrical properties.

Innovation Solution

The method involves growing and aligning carbon nanotubes on a substrate, transferring them to form a uniform interface between materials, and binding them to enhance mechanical, thermal, and electrical properties of composite articles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional CNT synthesis methods are used, then CNT structures are formed, but the CNTs have large diameter and insufficient length resulting in poor alignment

Engineering Contradiction:
ImproveCNT alignmentVSAvoidCNT structure quality
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by first forming a catalyst layer on the substrate before synthesizing CNTs. The catalyst layer is prepared in advance with specific patterns and compositions that pre-determine the CNT growth characteristics, ensuring proper alignment and dimensions before the actual CNT synthesis occurs. This preliminary catalyst preparation resolves the contradiction by establishing the foundation for high-quality CNT structures before the synthesis process begins.

Inventive Principle:
Principle #10Preliminary action

2Stability of the object's composition

If CNTs are dispersed in secondary materials, then composite materials are formed, but CNT agglomeration hinders uniform wetting and dispersion

Engineering Contradiction:
ImproveCNT dispersion uniformityVSAvoidCNT processing
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent applies local quality by creating spatially varying catalyst distributions and CNT structures. Different regions of the substrate receive different catalyst compositions or densities, which produce CNTs with locally optimized properties for dispersion. This local variation in catalyst quality prevents uniform agglomeration by creating natural dispersion gradients, resolving the contradiction between composition stability and manufacturing ease.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses the catalyst layer as an intermediary between the substrate and the CNTs. The catalyst mediates the synthesis process by controlling nucleation and growth patterns, ensuring that CNTs form with properties that facilitate uniform dispersion in secondary materials. This intermediary catalyst layer resolves the contradiction by providing a controlled interface that prevents direct agglomeration issues.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Strength

If CNT alignment is attempted in systems with large advanced fibers, then reinforcement is achieved, but alignment of nanotubes in the secondary material remains difficult

Engineering Contradiction:
Improvecomposite reinforcementVSAvoidCNT alignment in matrix
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent applies dimensionality change by forming CNTs with specific aspect ratios and orientations that bridge the gap between 2D fiber surfaces and 3D matrix volumes. The CNTs are grown with controlled lengths and diameters that allow them to span multiple dimensions, connecting fibers to the surrounding matrix effectively. This dimensional approach resolves the contradiction by providing reinforcement that operates across multiple spatial scales simultaneously.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in composite materials with improved mechanical strength, thermal conductivity, and electrical properties by ensuring uniform alignment and dispersion of carbon nanotubes within the material structure.

Implementation Method 1

The catalyst material may be iron, ruthenium, osmium, cobalt, rhodium, iridium, nickel, palladium, or platinum, or a combination thereof

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS11458718B2Nanostructure-reinforced composite articles and methods
Publication Date: 2022.10.04 MASSACHUSETTS INST OF TECH
  • US11458718B2 patent drawing
  • US11458718B2 patent drawing
  • US11458718B2 patent drawing

AI summary

The present invention provides methods for uniform growth of nanostructures such as nanotubes (e.g., carbon nanotubes) on the surface of a substrate, wherein the long axes of the nanostructures may be substantially aligned. The nanostructures may be further processed for use in various applications, such as composite materials. For example, a set of aligned nanostructures may be formed and transferred, either in bulk or to another surface, to another material to enhance the properties of the material. In some cases, the nanostructures may enhance the mechanical properties of a material, for example, providing mechanical reinforcement at an interface between two materials or plies. In some cases, the nanostructures may enhance thermal and/or electronic properties of a material. The present invention also provides systems and methods for growth of nanostructures, including batch processes and continuous processes.