Aliphatic Hydrocarbon Thickening Agent Viscosity Control

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Solution Overview

Problem

Existing thickening/stabilizing agents, such as 12-hydroxystearic acid, cannot adjust the viscosity of fluid organic substances to a desired level and often result in either a completely solidified or liquid state, failing to maintain uniform stability and transparency in compositions.

Innovation Solution

Compounds with a specific structure, represented by Formula (R2—HNOC)4-n—R1—(CONH—R3)n, where R1, R2, and R3 are aliphatic hydrocarbon groups, are used to thicken fluid organic substances to a desired viscosity, preventing sedimentation and maintaining uniform stability by dissolving in the substances and forming a fibrous self-assembled structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If 12-hydroxystearic acid is used as a thickening/stabilizing agent for fluid organic substances, then the substance can be thickened, but the degree of gelling is unadjustable and the substance can only be brought into either a completely solidified state or a liquid state

Engineering Contradiction:
Improveadjustability of viscosityVSAvoidrange of viscosity control
Core Design Contradiction:
Ease of operationVSAdaptability or versatility

Solution Approach 1:

The patent applies parameter changes by modifying the molecular structure of the thickening agent through varying the carbon chain lengths (R1: 4-20 carbons, R2: 4-20 carbons, R3: 4-20 carbons) and hydrogen content of aliphatic hydrocarbon groups. This structural parameter variation enables continuous adjustment of thickening degree, allowing the fluid organic substance to achieve any desired viscosity between liquid and solid states, resolving the binary state limitation of 12-hydroxystearic acid

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining multiple aliphatic hydrocarbon groups with different properties (R1, R2, R3 groups with 4-20 carbon atoms each) into a single thickening agent molecule. This composite structure allows the agent to interact with fluid organic substances in a tunable manner, providing adjustable thickening effects that neither simple compounds like 12-hydroxystearic acid nor pure polymers can achieve alone

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If existing thickening agents are used, then thickening can be achieved, but uniform stability and transparency are not maintained in compositions

Engineering Contradiction:
Improveuniform stabilityVSAvoidsedimentation and local aggregation
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The patent uses parameter changes by optimizing the carbon chain length parameters (R1, R2, R3 groups with 4-20 carbons) to achieve optimal molecular size and hydrophobicity balance. This parameter optimization enables the thickening agent to form stable colloidal dispersions in fluid organic substances, preventing sedimentation and local aggregation while maintaining composition uniformity and transparency over time

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies the intermediary principle by using the aliphatic hydrocarbon groups (R1, R2, R3) as mediator structures that interact with both the thickening agent core and the fluid organic substance. These intermediary hydrocarbon chains act as compatibility bridges, ensuring uniform distribution and stable dispersion without causing sedimentation or aggregation, thereby maintaining composition stability and transparency

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compounds effectively adjust the viscosity of fluid organic substances, maintaining uniform stability and transparency, making them suitable for use in cosmetics, coating materials, and pharmaceutical preparations by imparting pseudoplastic behavior and high storage modulus.

Implementation Method 1

forming a fibrous self-assembled structure

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Implementation Method 2

dissolving in the substances

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 3

imparting pseudoplastic behavior

Methodology Applied
Scientific EffectPseudoplasticity: Non-Newtonian Fluids

Data Source

PatentUS10351513B2Thickening and stabilizing agent, and thickening and stabilizing composition using same
Publication Date: 2019.07.16 DAICEL CORP
  • US10351513B2 patent drawing
  • US10351513B2 patent drawing

AI summary

Provided are: a compound, a thickening/stabilizing agent including the compound, a thickened/stabilized composition including the thickening/stabilizing agent and a fluid organic substance, and a method for producing the thickened/stabilized composition, where the compound effectively thickens the fluid organic substance to a desired viscosity and effectively uniformly stabilizes the formulation of the composition containing the fluid organic substance via thickening of the fluid organic substance. The thickening/stabilizing agent according to the present invention includes a compound represented by Formula (1):(R2—HNOC)4-n—R1—(CONH—R3)n  (1)where R1 is a group resulting from removing four hydrogen atoms from the structural formula of butane; R2 and R3 are different from each other and are aliphatic hydrocarbon groups each containing 4 or more carbon atoms; and n is an integer of 1 to 3.