Alkaline Electrolyzer Cell Configuration for High-Pressure Hydrogen Production

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Solution Overview

Problem

Existing PEM-based electrolyzer configurations fail to meet DOE 2012 goals for cost, efficiency, and power density, particularly in producing hydrogen at $/kW, $/gge, and efficiency targets.

Innovation Solution

A high power density, low-cost alkaline electrolyzer configuration utilizing laminar flow forced recirculation and advanced materials like G-10 fiberglass and Ni-200 electrodes, capable of operating at up to 200 bar pressure, achieving 81% efficiency and reducing production costs to <$333/kW and $0.96/gge H2.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If PEM-based electrolyzer configurations are used, then hydrogen production capability is achieved, but cost exceeds DOE 2012 goals ($400/kW target)

Engineering Contradiction:
Improvehydrogen production capabilityVSAvoidcost
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent transitions from PEM technology to alkaline electrolysis, fundamentally changing the chemical parameters and operating conditions. This parameter change enables the use of less expensive materials and construction methods while maintaining hydrogen production capability, achieving costs below the DOE 2012 target of $400/kW

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs simpler, less expensive materials in the alkaline electrolyzer construction compared to PEM systems. By using readily available materials and simplified cell designs, the system achieves lower manufacturing costs while maintaining adequate performance and lifespan for the application

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Quantity of substance

If existing electrolyzer configurations are used, then hydrogen production is achieved, but efficiency falls short of DOE 2012 goals (69% target)

Engineering Contradiction:
Improvehydrogen productionVSAvoidefficiency
Core Design Contradiction:
Quantity of substanceVSLoss of energy

Solution Approach 1:

The patent optimizes operating parameters including temperature, pressure, and electrolyte composition to maximize efficiency. By carefully controlling these parameters and using alkaline chemistry instead of PEM, the system achieves efficiencies exceeding the DOE 2012 target of 69%

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If conventional electrolyzer designs are used, then operation is achieved, but power density is insufficient for high-performance applications

Engineering Contradiction:
Improveoperational capabilityVSAvoidpower density
Core Design Contradiction:
Ease of operationVSPower

Solution Approach 1:

The patent employs a flat-panel cell design that maximizes active electrode area within a compact footprint. This dimensional optimization, combined with optimized flow channels and electrode structures, achieves high power density suitable for high-performance fuel cell applications while maintaining ease of operation

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

4Device complexity

If low-pressure electrolysis is used, then simplicity is maintained, but ability to supply high-pressure hydrogen for fuel cells is insufficient

Engineering Contradiction:
Improvesystem simplicityVSAvoidhydrogen delivery pressure
Core Design Contradiction:
Device complexityVSStress or pressure

Solution Approach 1:

The patent integrates the electrolysis function with high-pressure gas generation capability in a single system design. By optimizing the cell structure and operating conditions, the system simultaneously achieves operational simplicity and the ability to deliver hydrogen at pressures up to 200 bar, eliminating the need for separate compression equipment in many applications

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The configuration significantly enhances power density and efficiency while reducing costs, enabling the production of hydrogen and oxygen gases at high pressures for use in fuel cells and energy storage, meeting or exceeding DOE 2012 goals with a projected cost of $0.96/kg H2, a 2.6-fold reduction below the target.

Implementation Method 1

An Alkaline Electrolyzer Cell Configuration (AECC) is disclosed which achieves high efficiency by use of laminar flow forced recirculation

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

An Alkaline Electrolyzer Cell Configuration (AECC) is disclosed which achieves high efficiency by use of laminar flow forced recirculation

Methodology Applied
Scientific EffectLaminar flow: Laminar Flow

Data Source

PatentUS8123915B2Alkaline electrolyzer
Publication Date: 2012.02.28 RICHARDS WILLIAM R
  • US8123915B2 patent drawing
  • US8123915B2 patent drawing
  • US8123915B2 patent drawing

AI summary

An Alkaline Electrolyzer Cell Configuration (AECC) has a hydrogen half cell; an oxygen half cell; a GSM (Gas Separation Membrane); two inner hydrogen half cell spacer screens; an outer hydrogen half cell spacer screen; a hydrogen electrode; two inner oxygen half cell spacer screens; an outer oxygen half cell spacer screen; and an oxygen electrode. The hydrogen half cell includes the hydrogen electrode which is located between said two inner hydrogen half cell spacer screens and said outer hydrogen half cell spacer screen. The oxygen half cell includes the oxygen electrode which is located between said two inner oxygen half cell spacer screens and said outer oxygen half cell spacer screen. The GSM is provided between said two inner hydrogen half cell spacer screens of the hydrogen half cell and said two inner oxygen half cell spacer screens of the oxygen half cell to from the electrolyzer.