Alkaline Etching Composition for Selective Silicon Removal

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Solution Overview

Problem

Current etching processes for semiconductor manufacturing struggle to selectively remove silicon from objects containing both silicon and silicon-germanium, requiring a composition that can differentiate between these materials effectively.

Innovation Solution

A composition comprising a specific compound with two or more sulfur atoms and heteroatoms, an organic solvent, and water, which is alkaline, including a disulfide group and polar groups like amino, hydroxy, or carbonyl groups, along with a quaternary ammonium salt, is used to selectively remove silicon from objects containing silicon-germanium and silicon.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional etching processes are used, then etching can be performed, but selective removal of silicon from silicon-germanium is insufficient

Engineering Contradiction:
Improveselective removal capabilityVSAvoidmaterial differentiation accuracy
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the etching solution by incorporating specific compounds (thiol compounds, sultone compounds, or sulfonic acid compounds) along with organic solvents and water. This compositional parameter change enables the etching solution to selectively remove silicon while preserving silicon-germanium, resolving the contradiction between etching capability and selective removal precision.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite etching solution system combining multiple components: specific sulfur-containing compounds (thiol, sultone, or sulfonic acid compounds), organic solvents (such as alcohols, ketones, or esters), and water. This composite material approach enhances the selective etching performance by leveraging the synergistic effects of different components, achieving both etching effectiveness and material differentiation.

Inventive Principle:
Principle #40Composite materials

2Productivity

If existing chemical liquids are used for etching, then the etching process can proceed, but the ability to selectively remove only specific materials is inadequate

Engineering Contradiction:
Improveetching efficiencyVSAvoidselectivity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent modifies the chemical parameters of the etching solution by specifying particular compounds with sulfur functional groups (thiol, sultone, or sulfonic acid groups) combined with organic solvents. This parameter optimization maintains high etching efficiency while achieving superior selectivity for removing silicon over silicon-germanium.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional etching chemistry with a specialized chemical system based on sulfur-containing compounds. This substitution creates new chemical interaction mechanisms that provide both high etching rates and excellent selectivity, overcoming the limitations of traditional etching solutions.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves enhanced selective removal of silicon while minimizing the etching of silicon-germanium, thereby improving the semiconductor manufacturing process by providing superior Si selective removal properties and SiGe anticorrosion properties.

Implementation Method 1

it is common to carry out an etching process using a chemical liquid... an etchant is disclosed that contains water, at least one of a quaternary ammonium compound or an amine compound

Methodology Applied
Scientific EffectChemical etching: Chemical Bonding

Implementation Method 2

desirable that the chemical liquid used for etching is a chemical liquid capable of selectively removing only a specific material... capable of selectively removing silicon with respect to silicon-germanium

Methodology Applied
Scientific EffectSelective removal: Adsorption

Implementation Method 3

an etchant is disclosed that contains water, at least one of a quaternary ammonium compound or an amine compound, and a water-miscible solvent

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentUS20240425754A1Composition for manufacturing semiconductor, method for treating object to be treated, and method for manufacturing semiconductor element
Publication Date: 2024.12.26 FUJIFILM CORP
  • US20240425754A1 patent drawing
  • US20240425754A1 patent drawing
  • US20240425754A1 patent drawing

AI summary

An object of the present invention is to provide a composition for manufacturing a semiconductor, which is capable of selectively removing silicon in a case of being applied to an object to be treated containing silicon-germanium and silicon; a method for treating an object to be treated using the composition for manufacturing a semiconductor; and a method for manufacturing a semiconductor element using the composition for manufacturing a semiconductor.The composition for manufacturing a semiconductor according to the present invention is a composition which includes a specific compound having two or more sulfur atoms and one or more heteroatoms other than a sulfur atom, an organic solvent, and water, and is alkaline.