Alkane Diols Suppress Salt Crystals in Cosmetic Preparations

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Solution Overview

Problem

Cosmetic preparations containing sodium chloride often face issues with salt crystal formation, especially in cleansing wipes, leading to phase separation and poor packaging re-closure due to desiccation, which affects their stability and effectiveness.

Innovation Solution

A cosmetic preparation combining one or more alkane diols such as propylene glycol, butylene glycol, and sodium chloride at specific concentrations (0.25-5% by weight) to suppress salt crystal formation, allowing for higher stable sodium chloride incorporation, thereby enhancing microbial stability and barrier lipid content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If sodium chloride is incorporated into cosmetic preparations at higher concentrations, then the cosmetic effectiveness is improved, but salt crystal formation occurs due to desiccation

Engineering Contradiction:
Improvesodium chloride contentVSAvoidsalt crystal formation
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent introduces alkane diols as intermediary substances that mediate between sodium chloride and water. These diols form hydrogen bonds with water molecules, creating a protective solvation shell around the salt ions and preventing direct crystallization. This intermediary mechanism allows high concentrations of sodium chloride (up to 5% or more) to remain stable in aqueous cosmetic preparations without forming disruptive salt crystals during storage or application.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If cleansing wipes are presented in large quantities in storage containers, then the availability for use is improved, but salt crust formation is enhanced due to large surface area drying out quickly

Engineering Contradiction:
Improveavailability of cleansing wipesVSAvoidsalt crust formation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the impregnation solution by incorporating specific alkane diols (such as propylene glycol, butylene glycol, or their mixtures) at optimized concentrations. This parameter change modifies the evaporation kinetics and crystallization behavior of the salt solution. The diols reduce the rate of water evaporation from the wipe surface and alter the supersaturation dynamics, preventing salt crust formation even when large quantities of wipes are stored in non-hermetic containers with significant exposed surface area.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If salt crystals form at dispensing apertures, then the packaging re-closure becomes poorer, but the salt crystal formation is enhanced by the phenomenon itself

Engineering Contradiction:
Improvepackaging re-closureVSAvoidsalt crystal formation at apertures
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent applies preliminary action by incorporating alkane diols into the salt-containing preparation before packaging. This pre-treatment ensures that the salt remains in solution form throughout storage and usage. When the preparation is dispensed through the aperture, the diols continue to prevent crystallization during the dispensing process, ensuring clean aperture edges that maintain good sealing contact for re-closure. The preliminary presence of diols prevents the self-enhancing salt crystal formation that would otherwise occur at the aperture interface.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination significantly reduces salt crystal formation, enabling more effective and stable cosmetic preparations with increased microbial stability and improved barrier lipid content in the stratum corneum, even in desiccation conditions.

Implementation Method 1

the formation of salt crystals is suppressed to such an extent that it is also possible to incorporate significantly higher concentrations of sodium chloride in the preparations in a stable (in particular desiccation-stable) form

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 2

one or more alkane diols selected from the group of the compounds propylene glycol, butylene glycol, 2-methylpropane-1,3-diol, glyceryl caprylate, polyglyceryl-2 caprate, ethylhexylglycerin, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol and/or 1,2-decanediol

Methodology Applied
Scientific EffectHydrogen bonding:

Data Source

PatentUS12042551B2Alkane diols in salt-containing cosmetic preparations
Publication Date: 2024.07.23 BEIERSDORF AG

AI summary

Cosmetic preparation containing a) one or more alkane diols selected from the group of the compounds propylene glycol, butylene glycol, 2-methylpropane-1,3-diol, ethylhexylglycerol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol and/or 1,2-decanediol, and b) sodium chloride in a concentration of 0.25 to 5% by weight, based on the total weight of the preparation.