Metal Alkoxylate Charge Adjuvants for Electrostatic Ink

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Solution Overview

Problem

Existing electrostatic ink toner technologies, particularly those using aluminum stearate as a charge adjuvant, face limitations in tuning physical and electrical characteristics, leading to suboptimal printing quality and increased complexity due to heterogeneous powder dispersion and high charge adjuvant concentrations.

Innovation Solution

The use of metal alkoxylate compounds, such as aluminum monostearate monobenzoate hydroxide (ASBH), as a charge adjuvant replaces aluminum stearate, allowing for homogeneous addition after grinding and enabling the tuning of viscosity and electrical characteristics, reducing the amount of charge adjuvant needed and simplifying the production process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If aluminum stearate is used as charge adjuvant, then charge adjuvant function is provided, but homogeneous dispersion is difficult and high concentration is required

Engineering Contradiction:
Improvecharge adjuvant concentrationVSAvoidhomogeneity of dispersion
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical parameters of the charge adjuvant from aluminum stearate to metal alkoxylate compounds (aluminum alkoxides). This parameter change enables the charge adjuvant to be added in lower concentrations (0.01-5% by weight) while achieving homogeneous dispersion, resolving the contradiction between quantity and homogeneity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the traditional aluminum stearate with metal alkoxylate compounds that can be added as liquids or fine powders and fully dissolved or dispersed in the carrier liquid. This substitution allows for more efficient utilization of the charge adjuvant, reducing the required concentration while maintaining homogeneous composition throughout the electrostatic ink.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Adaptability or versatility

If aluminum stearate is used as charge adjuvant, then charge function is provided, but tuning of physical and electrical characteristics is limited

Engineering Contradiction:
Improvetunability of viscosity and electrical characteristicsVSAvoidcharge adjuvant concentration
Core Design Contradiction:
Adaptability or versatilityVSQuantity of substance

Solution Approach 1:

The patent employs metal alkoxylate compounds with variable metal components (alkali, alkaline earth, transition metals) and variable alkoxide groups (linear, branched, cyclic, aromatic). By changing these parameters, the viscosity and electrical characteristics of the electrostatic ink can be precisely tuned to match specific printing requirements, while using lower charge adjuvant concentrations compared to aluminum stearate.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite charge adjuvant systems by combining metal alkoxylate compounds with charge directors and other additives in the electrostatic ink formulation. This composite approach enables independent optimization of viscosity control and electrical charge properties, providing enhanced adaptability while reducing the overall concentration of charge adjuvant materials needed.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If heterogeneous powder dispersion is used, then charge adjuvant function is provided, but production complexity increases

Engineering Contradiction:
Improvesimplicity of production processVSAvoidhomogeneity of charge adjuvant distribution
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent replaces heterogeneous powder dispersion with homogeneous liquid or fine powder metal alkoxylate compounds that can be easily mixed into the carrier liquid. This substitution simplifies the manufacturing process by eliminating the need for complex dispersion equipment and processes, while ensuring uniform charge adjuvant distribution throughout the electrostatic ink formulation.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent utilizes the liquid or fine powder form of metal alkoxylate compounds that can be readily incorporated into the carrier liquid through standard mixing and homogenization equipment. This hydraulic approach to charge adjuvant incorporation simplifies production by leveraging fluid dynamics for uniform distribution, reducing manufacturing complexity compared to heterogeneous powder dispersion methods.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in superior electrical properties, improved batch repeatability, and the ability to produce high-quality ink toners with adjustable viscosity and conductivity, enhancing printing performance and reducing costs by allowing for lower charge adjuvant concentrations and flexible addition protocols.

Implementation Method 1

a charge adjuvant, a carrier liquid, a resin, a pigment, and a charge director, wherein the charge adjuvant is a metal alkoxylate compound

Methodology Applied
Scientific EffectCharge adjuvant effect:

Implementation Method 2

The liquid image is attracted from the photoconductive surface to the surface of the intermediate transfer member

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Data Source

PatentUS7736829B2Charge adjuvants in electrostatic inks
Publication Date: 2010.06.15 HEWLETT PACKARD DEVELOPMENT COMPANY LP
  • US7736829B2 patent drawing
  • US7736829B2 patent drawing
  • US7736829B2 patent drawing

AI summary

Ink toners, electroink compositions, methods of making ink toners, methods of making electroink compositions, and the like, are described.