Alkoxylated Amine Additives for Bitumen Workability and Stripping

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Solution Overview

Problem

Existing bitumen-based paving technologies require high temperatures for mixing, transportation, and compaction, leading to energy consumption and moisture-related issues like stripping and loss of cohesive strength, while current warm-mix additives do not adequately address these problems.

Innovation Solution

The use of alkoxylated amines as additives in bitumen compositions to lower processing temperatures while enhancing anti-stripping properties and maintaining cohesive strength, thereby reducing the loss of stiffness modulus.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If high temperatures are used for mixing, transportation, and compaction of bitumen, then workability of the asphalt composition is improved, but energy consumption increases and moisture damage (stripping) worsens

Engineering Contradiction:
Improveworkability of asphalt compositionVSAvoidenergy consumption
Core Design Contradiction:
Ease of operationVSLoss of energy

Solution Approach 1:

The invention changes the chemical composition parameters of the bituminous binder by adding specific additives (soap, amine, and aromatic hydrocarbon in controlled ratios) to modify the rheological properties of bitumen, enabling it to maintain workability at lower temperatures without sacrificing operational ease

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite bituminous binder system by combining bitumen with a specific formulation of additives (soap, amine, and aromatic hydrocarbon), where the synergistic interaction of components enables both reduced processing temperature and maintained workability

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If high temperatures are used for mixing, transportation, and compaction of bitumen, then workability of the asphalt composition is improved, but moisture damage (stripping) worsens

Engineering Contradiction:
Improveworkability of asphalt compositionVSAvoidresistance to stripping
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The invention modifies the chemical parameters of the bituminous binder through controlled addition of additives, changing the interaction mechanisms between bitumen, aggregate, and water to prevent stripping while maintaining workability at reduced temperatures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The additives (particularly the soap and amine components) act as intermediary substances that mediate between the bitumen and aggregate surfaces, enhancing adhesion and preventing water from displacing the bituminous binder, thereby improving reliability against stripping

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If high temperatures are used for processing bitumen, then workability is improved, but cohesive strength of the bituminous binder decreases

Engineering Contradiction:
ImproveworkabilityVSAvoidcohesive strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The invention changes the thermal and rheological parameters of the bituminous binder through additive formulation, allowing the material to maintain appropriate viscosity and workability at lower temperatures while preserving cohesive strength that would otherwise be degraded by high-temperature processing

Inventive Principle:
Principle #35Parameter changes

4Loss of energy

If processing temperatures are reduced using warm-mix additives, then energy consumption decreases, but stiffness modulus of the pavement is reduced

Engineering Contradiction:
Improveenergy consumptionVSAvoidstiffness modulus
Core Design Contradiction:
Loss of energyVSStrength

Solution Approach 1:

The invention carefully controls the chemical composition parameters of the additives and their ratios to modify bitumen properties in a way that reduces processing temperature requirements while minimizing negative impacts on the stiffness modulus of the resulting pavement

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies different functional components locally within the bituminous binder system, where specific additives (soap, amine, aromatic hydrocarbon) perform specialized functions that collectively reduce processing temperature while maintaining overall pavement stiffness

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS9534146B2Additives for bitumen containing compositions
Publication Date: 2017.01.03 AKZO NOBEL CHEMICALS INTERNATIONAL BV
  • US9534146B2 patent drawing
  • US9534146B2 patent drawing

AI summary

The present invention relates to a composition comprising bitumen and an alkoxylated amine, to a method for the production of such a composition, and to a method for paving a surface using such a composition. The present invention also relates to an preformulated additive package to be added to bitumen, comprising an alkoxylated amine and an anti-stripping agent.