Alkylation Reactor Dual Mode Operation with Ionic Liquid Catalyst

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Solution Overview

Problem

Current processes for producing gasoline blending components struggle to efficiently produce high-quality products with desired Research Octane Numbers (RON) and sulfur levels, particularly in switching between alkylate and distillate modes, which affects product yield and quality.

Innovation Solution

An alkylation reactor system that operates in both alkylate and distillate modes using an acidic ionic liquid catalyst, with a control system to adjust process conditions such as conjunct polymer levels, halide containing additives, and isoparaffin to olefin ratios, enabling the production of gasoline blending components with RON of 90 or higher and distillate products with RON of 85 or higher, while maintaining low sulfur levels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If an alkylation reactor operates in alkylate mode to produce high RON gasoline blending components, then the RON of the gasoline blending component is 90 or higher, but the ability to produce distillate products is limited

Engineering Contradiction:
ImproveRON of gasoline blending componentVSAvoidmode switching capability
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The alkylation reactor is designed to perform multiple functions by operating in two distinct modes: alkylate mode for producing high RON gasoline blending components and distillate mode for producing distillate products. The reactor maintains universal applicability through a common reaction system that can be switched between modes by adjusting operational parameters such as temperature, pressure, and feedstock ratios, eliminating the need for separate dedicated reactors for each product type

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Adaptability or versatility

If process conditions are adjusted to switch between alkylate and distillate modes, then product flexibility is improved, but the complexity of controlling conjunct polymer levels and additive ratios increases

Engineering Contradiction:
Improvemode switching capabilityVSAvoidcontrol system complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The control system manages mode transitions by systematically adjusting key operational parameters including temperature, pressure, conjunct polymer levels, and halide-containing additive ratios. These parameter changes enable the reactor to switch between alkylate and distillate modes while maintaining product quality specifications, with the control system monitoring and regulating each parameter to achieve the desired operational state

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the reactor operates in distillate mode to produce distillate products, then distillate yield is increased, but the RON of the gasoline blending component decreases to 85 or higher

Engineering Contradiction:
Improvedistillate production volumeVSAvoidRON of gasoline blending component
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The reactor operates dynamically by allowing the RON specification for gasoline blending components to vary according to the operational mode. In distillate mode, the system accepts a lower RON threshold (85 or higher) compared to alkylate mode (90 or higher), enabling flexible production scheduling that prioritizes distillate yield when market conditions favor distillate products while maintaining acceptable product quality standards

Inventive Principle:
Principle #15Dynamics

4Manufacturing precision

If halide containing additives and conjunct polymer levels are controlled to maintain low sulfur levels, then product purity is improved, but the complexity of process control increases

Engineering Contradiction:
Improvesulfur level controlVSAvoidprocess control complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The control system implements feedback mechanisms to monitor and regulate sulfur levels by tracking conjunct polymer levels and halide-containing additive ratios. This feedback control enables the system to maintain low sulfur specifications in both alkylate and distillate products by automatically adjusting operational parameters based on real-time measurements, ensuring consistent product purity while managing control complexity through systematic parameter interrelationships

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively produces high-quality gasoline blending components and distillate products with desired RON and low sulfur levels, allowing for flexible operation between alkylate and distillate modes to meet market demands and product pricing shifts.

Implementation Method 1

An alkylation reactor system that operates in both alkylate and distillate modes using an acidic ionic liquid catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS8936768B2Alkylation process unit for producing high quality gasoline blending components in two modes
Publication Date: 2015.01.20 CHEVRON USA INC
  • US8936768B2 patent drawing
  • US8936768B2 patent drawing
  • US8936768B2 patent drawing

AI summary

We provide an alkylation process unit, comprising: a control system connected to an alkylation reactor, that enables the alkylation reactor to operate in both an alkylate mode that produces a gasoline blending component having a RON of 90 or higher and in a distillate mode that produces a second gasoline blending component having a RON of 85 or higher.