All-Electron Battery with Nanostructured Electrodes

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Solution Overview

Problem

Current energy storage devices, such as batteries and capacitors, face limitations in energy density, charge/discharge speed, and lifespan due to ion transport and chemical reactions, which restrict the performance of mobile devices and vehicles.

Innovation Solution

The All-Electron Battery (AEB) technology combines electron tunneling through a dielectric structure between electrodes with micro-structuring or nano-structuring of electrodes to enhance charge storage density and reduce self-discharge, utilizing inclusions and functional layers to achieve high energy and power density without chemical reactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If ion transport is used in batteries to store energy, then energy storage capacity is achieved, but charge/discharge speed becomes slow and degradation rate increases

Engineering Contradiction:
Improveenergy storage capacityVSAvoidcharge/discharge speed
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent replaces the electrochemical ion transport mechanism with a purely electronic charge storage mechanism. Electrons are injected into and extracted from quantum dot inclusions through quantum tunneling and thermal emission, eliminating the need for ion diffusion through electrolytes. This substitution of mechanical/electrical processes for electrochemical processes enables fast charge/discharge rates while maintaining high energy density.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental parameter of charge carrier type from ions to electrons, and changes the storage mechanism from bulk electrochemical reactions to surface-bound electron accumulation on quantum dots. This parameter change enables simultaneous achievement of high energy density (through quantum confinement effects) and high power density (through rapid electron transport).

Inventive Principle:
Principle #35Parameter changes

2Device complexity

If conventional capacitor plates with limited area are used, then device geometry is simple, but energy storage density is limited

Engineering Contradiction:
Improvedevice geometryVSAvoidenergy storage density
Core Design Contradiction:
Device complexityVSQuantity of substance

Solution Approach 1:

The patent employs quantum dot inclusions embedded in a dielectric matrix, creating a porous-like structure at the nanoscale. The quantum dots provide high surface area to volume ratio, enabling increased charge storage capacity within a compact geometric footprint. This nanoscale porosity allows electrons to be stored throughout the bulk volume rather than only at electrode surfaces.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent transitions from two-dimensional surface charge storage in conventional capacitors to three-dimensional bulk charge storage using quantum dot inclusions distributed throughout the dielectric volume. This dimensional transition enables energy storage density to scale with volume rather than surface area, dramatically increasing storage capacity.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Quantity of substance

If batteries use large size and weight of ions for energy storage, then energy is stored, but storage density per weight becomes low

Engineering Contradiction:
Improveenergy storageVSAvoidstorage density per weight
Core Design Contradiction:
Quantity of substanceVSWeight of moving object

Solution Approach 1:

The patent replaces heavy ion-based electrochemical storage with lightweight electron-based storage. Electrons have negligible mass compared to ions, enabling high energy density on a weight basis. The quantum dot inclusions provide efficient electron trapping sites without requiring heavy ion-containing electrolytes or electrode materials.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Quantity of substance

If electrochemical reactions with ion motion are employed, then energy storage is achieved, but response time becomes slow

Engineering Contradiction:
Improveenergy storageVSAvoidresponse time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The patent replaces slow ion diffusion and electrochemical reaction processes with rapid electron transport processes. Electrons can be injected into and extracted from quantum dots through quantum tunneling and thermal emission mechanisms that occur on timescales of microseconds or faster, eliminating the seconds-to-hours response times characteristic of electrochemical batteries.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

AEBs provide high energy density, fast charge/discharge rates, and extended lifespan with reduced degradation, enabling lightweight, high-capacity energy storage for applications like electric vehicles and portable electronics without the risks associated with ion-based batteries.

Implementation Method 1

Electrons can tunnel through the dielectric between the electrodes and the inclusions, thereby increasing the charge storage density relative to a conventional capacitor

Methodology Applied
Scientific EffectElectron tunneling:

Data Source

PatentUS8524398B2All-electron battery having area-enhanced electrodes
Publication Date: 2013.09.03 THE BOARD OF TRUSTEES OF THE LELAND STANFORD JUNIOR UNIV
  • US8524398B2 patent drawing
  • US8524398B2 patent drawing
  • US8524398B2 patent drawing

AI summary

Improved energy storage is provided by exploiting two physical effects in combination. The first effect can be referred to as the All-Electron Battery (AEB) effect, and relates to the use of inclusions embedded in a dielectric structure between two electrodes of a capacitor. Electrons can tunnel through the dielectric between the electrodes and the inclusions, thereby increasing the charge storage density relative to a conventional capacitor. The second effect can be referred to as an area enhancement effect, and relates to the use of micro-structuring or nano-structuring on one or both of the electrodes to provide an enhanced interface area relative to the electrode geometrical area. Area enhancement is advantageous for reducing the self-discharge rate of the device.