Aluminum Alloy Brazing Sheet for Uniform Flux-Free Fillet Formation

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Solution Overview

Problem

Current methods for brazing aluminum alloys without flux in an inert gas atmosphere face challenges such as inferior fillet formation and high maintenance costs due to the need for expensive vacuum equipment and difficulties in exposing the molten brazing material's surface effectively, leading to distorted or incomplete joints.

Innovation Solution

An aluminum alloy brazing sheet with a core material and a brazing material containing Si and specific atoms like Mg, Li, Be, Ca, Ce, La, Y, and Zr, which form oxide particles with a volume change ratio of 0.99 or lower, allowing for effective exposure of the molten brazing material's surface during brazing heating in an inert gas atmosphere without flux.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If flux is used in a nitrogen gas furnace to break the oxide film, then the oxide film can be effectively broken, but the cost of flux and the cost of the process of applying the flux increase

Engineering Contradiction:
Improveoxide film breaking effectivenessVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention extracts and eliminates the flux component from the brazing system by using a brazing material containing Mg that can break the oxide film through vaporization and reaction during heating, thereby removing the need for separate flux application processes and reducing manufacturing costs

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The brazing material contains Mg that automatically breaks the oxide film through vaporization and chemical reaction during the brazing heating process itself, making the oxide film breaking function self-contained within the brazing material rather than requiring external flux

Inventive Principle:
Principle #25Self-service

2Reliability

If a brazing material formed of Al—Si—Mg based alloy is used in a vacuum heating furnace, then the oxide film can be broken by vaporized Mg, but expensive vacuum heating equipment is required and high maintenance cost is needed to remove Mg adhering to the inside of the furnace

Engineering Contradiction:
Improveoxide film breaking effectivenessVSAvoidequipment cost and maintenance
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention uses a nitrogen gas atmosphere instead of vacuum for heating, allowing the brazing material to break the oxide film through Mg vaporization while avoiding the need for expensive vacuum equipment and its associated maintenance requirements

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The invention accepts that Mg will vaporize and adhere to the furnace interior as a temporary, manageable issue rather than requiring expensive vacuum equipment, treating the Mg adhesion as a short-term problem that can be cleaned during routine maintenance

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If Mg is included in a brazing material to enable surface joining, then the oxide film can be broken, but the oxide film is divided into particles and a newly formed surface is exposed by external force, causing formation of a distorted fillet in a practical joint

Engineering Contradiction:
Improvesurface joining capabilityVSAvoidfillet uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The invention changes the parameters of the brazing material by specifying precise Si content (4.0-13.0 mass%) and Mg content (0.01-2.0 mass%), along with controlled oxide film thickness (5-30 nm), to achieve uniform fillet formation without distortion while maintaining effective oxide film breaking

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite brazing material system combining Al-Si-Mg alloy with controlled oxide film and specific additive elements (Ca, Ce, La, Y, Zr, Be) to achieve both effective oxide film breaking and uniform fillet formation that neither component could achieve alone

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables excellent brazability by ensuring uniform exposure of the brazing material's surface, resulting in high-quality joints with improved corrosion resistance and reduced maintenance costs, as the oxide particles effectively break the oxide film without the need for flux or expensive vacuum equipment.

Implementation Method 1

Mg in the brazing material is vaporized by heating in vacuum, to break the oxide film on the surface of the material

Methodology Applied
Scientific EffectVaporization: Evaporation

Implementation Method 2

the vaporized Mg adheres to the inside of the furnace

Methodology Applied
Scientific EffectAdhesion: Adsorption

Implementation Method 3

flux reacts with an oxide film during brazing heating, and breaks the oxide film

Methodology Applied
Scientific EffectChemical reaction: Redox Reactions

Data Source

PatentUS11813687B2Aluminum alloy brazing sheet, method for manufacturing the same, aluminum alloy sheet, and heat exchanger
Publication Date: 2023.11.14 UACJ CORP
  • US11813687B2 patent drawing

AI summary

An aluminum alloy brazing sheet used for brazing in an inert gas atmosphere without using flux includes a core material of aluminum or aluminum alloy, and a brazing material of aluminum alloy including Si of 4.0 mass % to 13.0 mass % and cladding one side surface or both side surfaces of the core material. One or both of the core material and the brazing material includes any one or two or more types of X atoms (X is Mg, Li, Be, Ca, Ce, La, Y, and Zr). The aluminum alloy brazing sheet is a brazing sheet in which oxide particles including the X atoms and having a volume change ratio of 0.99 or lower with respect to an oxide film before brazing heating are formed on a surface thereof, by brazing heating.