AlN Electrostatic Chuck Flatness at High Temperature

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Solution Overview

Problem

During plasma processing of semiconductor substrates, deformation due to thermal expansion differences between layers leads to non-uniformity and material wastage, as existing electrostatic chucks fail to maintain substrate flatness at high temperatures.

Innovation Solution

An electrostatic chuck with a chuck body made of aluminum nitride, having specific volume resistivity and heat conductivity values, embedded electrodes, and a dielectric material with controlled resistivity, which maintains the substrate flat and parallel by inducing opposite charge polarity for continuous Columbic attraction, and incorporates heating elements and protection circuitry for stable operation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If an electrostatic chuck is used to clamp the substrate, then the substrate is held flat during processing, but the substrate becomes deformed at high operating temperatures due to substrate surface stress changes

Engineering Contradiction:
Improvesubstrate flatnessVSAvoidoperating temperature
Core Design Contradiction:
ShapeVSTemperature

Solution Approach 1:

The patent applies parameter changes by utilizing the temperature-dependent electrical resistivity characteristics of aluminum nitride material. As temperature increases, the resistivity of AlN decreases, which enhances charge migration capability and maintains electrostatic clamping force effectiveness at high temperatures, thereby preserving substrate flatness despite thermal stress changes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces mechanical clamping systems with an electrostatic field-based clamping mechanism. By applying high voltage to the electrostatic chuck, electrical charges are induced on the substrate surface, creating attractive electrostatic forces that hold the substrate flat without mechanical contact, thus avoiding deformation issues associated with mechanical clamping at high temperatures

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Temperature

If the substrate is heated to high temperatures during plasma processing, then plasma enhanced deposition processes can be performed, but thermal expansion differences among layers cause substrate bowing and non-uniformity

Engineering Contradiction:
Improveprocessing temperatureVSAvoidsubstrate uniformity
Core Design Contradiction:
TemperatureVSShape

Solution Approach 1:

The patent applies the anti-weight principle by using electrostatic forces as a counteracting mechanism against thermal expansion-induced bowing. The electrostatic chuck generates attractive forces that oppose the tendency of the substrate to deform due to differential thermal expansion among layers, thereby maintaining substrate flatness and uniformity at high processing temperatures

Inventive Principle:
Principle #8Anti-weight (Counterweight)

3Loss of substance

If the substrate is not held flat during processing, then material wastage and contamination occur, but maintaining flatness requires sophisticated electrostatic control at high temperatures

Engineering Contradiction:
Improvematerial wastageVSAvoidelectrostatic control system
Core Design Contradiction:
Loss of substanceVSDevice complexity

Solution Approach 1:

The patent leverages parameter changes in the aluminum nitride material properties, specifically its resistivity-temperature relationship. The decrease in resistivity at high temperatures naturally enhances charge migration and electrostatic force generation, reducing the need for additional complex control mechanisms while maintaining substrate flatness and preventing material wastage

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The electrostatic chuck effectively maintains substrate flatness and parallelism, ensuring consistent processing conditions and reducing material wastage and contamination, while providing sufficient chucking force across a wide temperature range.

Implementation Method 1

charge migration and induced opposite charge polarity, thereby providing continuous Columbic attraction

Methodology Applied
Scientific EffectColumbic attraction: Coulomb's Law

Implementation Method 2

charge migration and induced opposite charge polarity

Methodology Applied
Scientific EffectCharge migration: Electrical Resistance

Implementation Method 3

heat conductivity value about 60 W/m-K and 190 W/m-K

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 4

Plasma provides many advantages in manufacturing semiconductor devices. For example, using plasma enables a wide range of applications due to lowered processing temperature

Methodology Applied
Scientific EffectPlasma heating: Plasma

Data Source

PatentUS10403535B2Method and apparatus of processing wafers with compressive or tensile stress at elevated temperatures in a plasma enhanced chemical vapor deposition system
Publication Date: 2019.09.03 APPLIED MATERIALS INC
  • US10403535B2 patent drawing
  • US10403535B2 patent drawing
  • US10403535B2 patent drawing

AI summary

Embodiments of the present disclosure provide an electrostatic chuck for maintaining a flatness of a substrate being processed in a plasma reactor at high temperatures. In one embodiment, the electrostatic chuck comprises a chuck body coupled to a support stem, the chuck body having a substrate supporting surface, and the chuck body has a volume resistivity value of about 1×107 ohm-cm to about 1×1015 ohm-cm in a temperature of about 250° C. to about 700° C., and an electrode embedded in the body, the electrode is coupled to a power supply. In one example, the chuck body is composed of an aluminum nitride material which has been observed to be able to optimize chucking performance around 600° C. or above during a deposition or etch process, or any other process that employ both high operating temperature and substrate clamping features.