AlNiCo Magnetic Particle Shells for Secure Infrared-Reflective Ink

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Solution Overview

Problem

Conventional magnetic particles face challenges in achieving uniform composition and size, leading to difficulties in distinguishing them from paramagnetic particles using high-priced recognition equipment, and they struggle with printability and infrared reflectivity, which compromises security features in security materials.

Innovation Solution

AlNiCo-based magnetic particles with a core particle composition of Al, Ni, and Co, coated with an inorganic shell, produced using a water-based atomization process to ensure uniformity and a specific particle size distribution, achieving coercivity, saturation magnetization, and infrared reflectance for enhanced security features.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If magnetic particles have high magnetization density, then security is improved, but it becomes difficult to measure a unique signal by high-priced recognition equipment

Engineering Contradiction:
ImprovesecurityVSAvoidsignal measurement
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The patent optimizes the magnetization density parameter to a specific range (0.3-1.5 emu/g) that balances security requirements with detectability by recognition equipment. This parameter change resolves the contradiction by finding the optimal value that satisfies both security and measurement needs

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If magnetic particles have large size, then it is easier to produce, but they cannot effectively reflect sunlight to conceal original dark colored particles

Engineering Contradiction:
Improveproduction easeVSAvoidsunlight reflection
Core Design Contradiction:
Ease of manufactureVSIllumination intensity

Solution Approach 1:

The patent specifies an optimal particle size range (3-15 μm) that balances manufacturability with sunlight reflection capability. This parameter optimization resolves the contradiction by identifying the size range where both production ease and optical concealment are satisfied

Inventive Principle:
Principle #35Parameter changes

3Reliability

If coercivity of magnetic particles is too high, then security is improved, but it becomes difficult to form uniform composition and size

Engineering Contradiction:
ImprovesecurityVSAvoidcomposition uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent optimizes coercivity to a specific range (50-200 Oe) that maintains security while enabling uniform composition and size formation. This parameter optimization resolves the contradiction by finding the coercivity range where both security and manufacturing precision are achieved

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The AlNiCo-based magnetic particles provide improved security by ensuring uniform magnetic properties, enhanced printability, and high infrared reflectivity, making them distinguishable only by high-priced recognition equipment and effectively concealing dark colors, thus improving the security of security materials.

Implementation Method 1

an atomization process is known as a method of producing magnetic particles having a certain size. The atomization process is classified into a gas atomization process, a water atomization process, and a mixed spraying process, depending on the kind of cooling media. Generally, in the atomization process, a molten alloy is sprayed into a cooling medium through a nozzle to allow a molten alloyalloy and the cooling medium to collide with each other to cool the droplets of the molten alloy

Methodology Applied
Scientific EffectAtomization:

Implementation Method 2

in the water atomization process, water (H 2 O) is used as a main cooling medium

Methodology Applied
Scientific EffectWater cooling: Cooling

Implementation Method 3

The AlNiCo-based magnetic particles provide improved security by ensuring uniform magnetic properties, enhanced printability, and high infrared reflectivity

Methodology Applied
Scientific EffectInfrared reflection: Reflection

Implementation Method 4

when ferromagnetic particles having a relatively large coercivity and soft-magnetic particles having a relatively small coercivity are mixed and formed into a certain shape or pattern

Methodology Applied
Scientific EffectFerromagnetism: Ferromagnetism

Data Source

PatentEP3712910B1Alnico-based magnetic particles for security ink
Publication Date: 2025.01.01 KOREA MINTING SECURITY PRINTING & ID CARD OPERATING CORP
  • EP3712910B1 patent drawingFigure 1
  • EP3712910B1 patent drawingFigure 2
  • EP3712910B1 patent drawingFigure 3

AI summary

AlNiCo-based magnetic particles according to the present invention are hard magnetic particles each comprising: a core particle containing Al, Ni, and Co; and an inorganic shell enclosing the core particle, wherein the core particle is an ultra-fine particle having D50 of smaller than 12 µm, D50 being particle size corresponding to 50% in the core particle diameter cumulative distribution, and wherein the core particle has a composition uniformity of equation 1, equation 2, and equation 3 below: 10≤UNFAl 10≤UNFNi 10≤UNFCo In equation 1, UNF (Al) is the value obtained by dividing the average Al composition among core particles by the standard deviation of the Al composition on the basis of weight% of the composition. In equation 2, UNF (Ni) is the value obtained by dividing the average Ni composition among core particles by the standard deviation of the Ni composition on the basis of weight% of the composition. In equation 3, UNF (Co) is the value obtained by dividing the average Co composition among core particles by the standard deviation of the Co composition on the basis of weight% of the composition.