Alpha-sialon Phosphor Slit Surface Fluorescence

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Solution Overview

Problem

The fluorescence characteristics of α-sialon phosphor particles vary based on their surface shape, and existing methods do not effectively enhance these characteristics beyond a specific wavelength range.

Innovation Solution

Forming at least one slit on the surface of α-sialon phosphor particles containing Eu, which improves the fluorescence characteristics by removing non-contributory phases and optimizing light incidence and emission.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If classification treatment by average particle diameter is performed to improve fluorescence characteristics, then fluorescence efficiency is improved, but the surface shape characteristics that contribute to fluorescence are not optimized

Engineering Contradiction:
Improvefluorescence characteristicsVSAvoidsurface shape control
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention applies local quality by creating slits at specific locations on the phosphor particle surface. The slits are formed at predetermined positions to control light incidence and emission angles locally, rather than uniformly treating the entire surface. This localized modification optimizes fluorescence characteristics by enhancing light extraction at critical interfaces while maintaining the bulk properties of the phosphor particle.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention transitions from controlling only particle size (one dimension) to controlling both particle size and surface topology (adding another dimension). By introducing slits that create three-dimensional surface features, the invention adds a new degree of freedom for optimizing fluorescence characteristics, allowing independent control of light interaction with the phosphor surface beyond what particle diameter classification alone can achieve.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Reliability

If slits are formed on the phosphor particle surface to optimize light incidence and emission, then fluorescence characteristics are improved, but manufacturing complexity increases

Engineering Contradiction:
Improvefluorescence characteristicsVSAvoidslit formation process
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention applies preliminary action by forming slits on the phosphor particle surface before the particles are incorporated into the final LED device. This pre-forming approach allows the slit structure to be established while particles are still in a manageable state, enabling subsequent handling and assembly processes to proceed without additional complex steps. The slits are created during a dedicated surface treatment stage, separating this function from the main phosphor synthesis process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention replaces complex mechanical slit formation methods with chemical etching or self-organized surface modification processes. Instead of using mechanical tools to create slits on hard phosphor particles, the invention employs chemical reactions or controlled surface treatments that naturally form the desired slit structures. This substitution of mechanical processes with chemical or self-organizing processes significantly reduces manufacturing complexity while achieving precise slit geometries.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Illumination intensity

If surface shape is modified to enhance fluorescence, then light emission characteristics are improved, but particle strength may be compromised

Engineering Contradiction:
Improvelight emission characteristicsVSAvoidparticle strength
Core Design Contradiction:
Illumination intensityVSStrength

Solution Approach 1:

The invention introduces a porous or slit-containing surface structure on the phosphor particles. These slits create controlled voids or channels on the particle surface that enhance light emission characteristics through improved light extraction and reduced total internal reflection. The porous surface structure increases the effective surface area for light interaction while maintaining adequate mechanical strength by keeping the slits shallow and strategically positioned, avoiding deep penetrations that would compromise particle integrity.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The slits enhance the fluorescence characteristics of α-sialon phosphor particles, maintaining the excitation wavelength range and improving light emission characteristics in light-emitting devices.

Implementation Method 1

a step of subjecting the α-sialon phosphor particle obtained by the pulverizing step to an acid treatment to form a slit on a surface of the α-sialon phosphor particle

Methodology Applied
Scientific EffectAcid treatment: Erosion

Implementation Method 2

an α-sialon phosphor particle containing Eu, in which at least one slit is formed on a surface of the α-sialon phosphor particle

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Data Source

PatentUS11339325B2Phosphor particle, composite, light-emitting device, and method for producing phosphor particle
Publication Date: 2022.05.24 DENKA CO LTD
  • US11339325B2 patent drawing
  • US11339325B2 patent drawing
  • US11339325B2 patent drawing

AI summary

An α-sialon phosphor particle containing Eu. At least one slit is formed on a surface of the α-sialon phosphor particle. The α-sialon phosphor particle is preferably produced by undergoing a raw material mixing step, a heating step, a pulverizing step, and an acid treatment step.