Alternating Layer Thermal Barrier Coatings for Sand Resistance

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Solution Overview

Problem

Turbine engine components in desert environments suffer from sand-related distress due to fluid sand deposits penetrating thermal barrier coatings, leading to spallation and accelerated oxidation of exposed metal, necessitating frequent repairs.

Innovation Solution

A thermal barrier coating system with alternating layers of oxyapatite and/or garnet combined with stabilized zirconia, hafnia, or titania materials, stabilized by rare earth oxides such as lanthanum, cerium, and praseodymium, which forms a barrier against molten sand infiltration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional thermal barrier coatings are used in desert environments, then the coating provides thermal insulation, but fluid sand deposits penetrate the coating causing spallation and accelerated oxidation

Engineering Contradiction:
Improvecoating durabilityVSAvoidsand penetration
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The coating is divided into multiple alternating layers of different materials (e.g., yttria-stabilized zirconia and garnet or oxyapatite) to create a composite structure. Each layer provides different functional properties, with the alternating arrangement creating a stepped morphology that mechanically interlocks and resists sand penetration while maintaining thermal insulation performance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses composite material systems combining ceramic materials with different properties. The alternating layers of zirconia-based and garnet or oxyapatite-based materials create a composite coating that leverages the thermal insulation properties of zirconia while the garnet/oxyapatite layers provide enhanced resistance to sand penetration and chemical stability.

Inventive Principle:
Principle #40Composite materials

2Device complexity

If single-layer thermal barrier coatings are used, then the coating structure is simple, but the coating is more susceptible to sand-related distress and spallation

Engineering Contradiction:
Improvecoating structureVSAvoidresistance to spallation
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The coating is divided into multiple alternating layers of different materials (e.g., yttria-stabilized zirconia and garnet or oxyapatite) to create a composite structure. Each layer provides different functional properties, with the alternating arrangement creating a stepped morphology that mechanically interlocks and resists sand penetration while maintaining thermal insulation performance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the coating have different material compositions and properties optimized for specific functions. The zirconia-based layers provide thermal insulation, while the garnet or oxyapatite layers provide enhanced mechanical interlocking and sand resistance. This local differentiation of material properties maximizes overall coating performance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating system effectively prevents molten silicate material penetration and enhances durability by forming a robust barrier against sand-induced distress, reducing maintenance and operational downtime.

Implementation Method 1

The coating system effectively prevents molten silicate material penetration and enhances durability by forming a robust barrier against sand-induced distress

Methodology Applied
Scientific EffectPhysical barrier formation:

Implementation Method 2

a stabilized material selected from the group consisting of zirconia, hafnia and titania, the stabilized material being stabilized by a rare earth material

Methodology Applied
Scientific EffectStabilization by rare earth material:

Implementation Method 3

Sand related distress is caused by the penetration of fluid sand deposits into the thermal barrier coatings which leads to spallation and accelerated oxidation of any exposed metal

Methodology Applied
Scientific EffectOxidation resistance: Oxidation

Data Source

PatentEP1900848B1Silicate resistant thermal barrier coating with alternating layers
Publication Date: 2013.10.23 UNITED TECH CORP
  • EP1900848B1 patent drawing

AI summary

A thermal barrier coating system for use on a turbine engine component which reduces sand related distress is provided. The coating system comprises at least one first layer of a stabilized material selected from the group consisting of zirconia, hafnia, and titania and at least one second layer containing at least one of oxyapatite and garnet. Where the coating system comprises multiple first layers and multiple second layers, the layers are formed or deposited in an alternating manner.