Alternating Semiconductor-Dielectric Phase Shift Mask

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Solution Overview

Problem

As semiconductor device feature sizes decrease, photolithography processes face challenges with optical fringing and diffraction effects, leading to distortion and increased critical dimension errors due to defects like crystal haze and particles in phase shift masks, particularly in molybdenum silicide-based masks.

Innovation Solution

A phase shift mask is developed using alternating semiconductor and dielectric layers, such as silicon and silicon dioxide, with controlled etch selectivities to reduce crystal haze and enhance physical damage resistance, along with a shading layer to improve light absorption and resolution, replacing traditional molybdenum silicide materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If molybdenum silicide-based phase shift masks are used, then phase shifting capability is achieved, but crystal haze and particle defects increase

Engineering Contradiction:
Improvephase shifting capabilityVSAvoidcrystal haze and particle defects
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent replaces single-material molybdenum silicide phase shifters with composite structures consisting of multiple semiconductor layers (e.g., silicon, germanium, silicon germanium) and dielectric layers (e.g., silicon dioxide, silicon nitride) stacked in alternating fashion. This composite structure achieves the required phase shifting capability while eliminating crystal haze and particle defects associated with molybdenum silicide.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the material composition parameters by transitioning from metallic molybdenum silicide to semiconductor-dielectric composites. This parameter change modifies the optical and physical properties of the phase shifter, achieving phase shifting through refractive index differences rather than metallic absorption, thereby eliminating harmful crystal haze effects.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If feature sizes decrease to increase density, then IC chip capacity increases, but optical fringing and diffraction effects worsen

Engineering Contradiction:
ImproveIC chip densityVSAvoidpattern transfer accuracy
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent segments the phase shifter into multiple thin alternating layers of semiconductor and dielectric materials. This segmentation creates a distributed phase shifting effect that better controls optical wavefronts, reducing fringing and diffraction effects at reduced feature sizes while maintaining pattern transfer accuracy.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the optical parameters of the phase shifter by using multi-layer semiconductor-dielectric structures with controlled thicknesses and refractive indices. This enables precise control of phase shifts and amplitude modulation, improving resolution and reducing optical artifacts at smaller feature dimensions.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If traditional single-layer phase shifters are used, then manufacturing process is simple, but etch selectivity control and profile quality are poor

Engineering Contradiction:
Improvephase shifter fabrication simplicityVSAvoidetch profile quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent segments the phase shifter into multiple alternating layers with different etch selectivities. This segmentation enables selective etching processes to create vertical sidewalls and precise profiles by exploiting the contrasting etch rates between semiconductor and dielectric layers, significantly improving profile quality despite increased structural complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses composite semiconductor-dielectric layers with deliberately chosen different etch selectivities. This composite structure allows sequential or selective removal of layers during fabrication, enabling precise control of phase shifter profiles and reducing defects while maintaining manufacturability through established multi-layer deposition and etching techniques.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enhances the precision and accuracy of pattern transfer during photolithography by reducing critical dimension errors and manufacturing defects, improving the yield and cost-effectiveness of semiconductor production.

Implementation Method 1

phase shift mask (PSM)... shift a phase of selected light passing through the photomask or the reticle by π (180 degrees)

Methodology Applied
Scientific EffectPhase shift: Interference

Implementation Method 2

The phase shifter includes a plurality of semiconductor layers and a plurality of dielectric layers arranged in an alternating fashion

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 3

a shading layer to improve light absorption and resolution

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 4

the undesired light is scattered or offset by the destructive interference

Methodology Applied
Scientific EffectDestructive interference: Interference

Data Source

PatentUS10852634B2Phase shifter mask
Publication Date: 2020.12.01 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US10852634B2 patent drawing
  • US10852634B2 patent drawing
  • US10852634B2 patent drawing

AI summary

A phase shift mask (PSM) includes a light transmitting substrate. The PSM further includes a phase shifter over the light transmitting substrate, wherein the phase shifter includes a plurality of semiconductor layers and a plurality of dielectric layers stacked in an alternating fashion.