Metal Gate Diffusion Barrier Layers for Stable Threshold Voltage

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Solution Overview

Problem

As integrated circuits downscale, the close proximity of nearby transistors leads to threshold voltage shifts due to aluminum diffusion between devices, degrading FET properties, particularly in 3D FETs where metal gate films play a crucial role in defining work function and threshold voltage.

Innovation Solution

Incorporating a diffusion barrier layer at the surface of aluminum-containing work function adjustment material layers to prevent aluminum diffusion into adjacent FETs, using Ti-rich, Ta-rich, or Si-doped layers to suppress aluminum migration and maintain device performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If aluminum-containing work function adjustment material layers are used to define gate properties, then work function and threshold voltage control is improved, but aluminum diffusion into adjacent FETs occurs causing threshold voltage shifts

Engineering Contradiction:
Improvethreshold voltage controlVSAvoidaluminum diffusion
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

A diffusion barrier layer is introduced as an intermediary between the aluminum-containing work function adjustment material layer and adjacent FETs. This barrier layer (comprised of Ti, Ta, W, Mo, or their nitrides/oxides) mediates the interaction by blocking aluminum diffusion while allowing the work function adjustment material to perform its intended function of defining gate properties and threshold voltage.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The gate structure is segmented into multiple functional layers: the work function adjustment material layer for electrical property control, and a separate diffusion barrier layer for protecting against aluminum migration. This segmentation allows each layer to independently perform its specific function without interfering with the other.

Inventive Principle:
Principle #1Segmentation

2Length of moving object

If transistor dimensions are downscaled to increase integration density, then device miniaturization is achieved, but aluminum diffusion effects are amplified due to closer proximity

Engineering Contradiction:
Improvetransistor dimensionVSAvoidaluminum diffusion effect
Core Design Contradiction:
Length of moving objectVSObject-generated harmful factors

Solution Approach 1:

The diffusion barrier layer serves as a protective intermediary that becomes increasingly critical as transistors are downscaled. By placing this barrier between adjacent miniaturized devices, the patent prevents aluminum diffusion effects from being amplified by the reduced spacing, thereby maintaining device performance in scaled technologies.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The diffusion barrier layer is applied in advance during the gate structure formation process, before aluminum diffusion can occur. This preliminary protective action prevents the harmful diffusion effect from manifesting, allowing continued downsscaling without suffering from aluminum migration issues.

Inventive Principle:
Principle #9Preliminary anti-action

3Reliability

If metal gate films are used to define work function and threshold voltage, then FET performance is improved, but aluminum diffusion between nearby FETs degrades device reliability

Engineering Contradiction:
ImproveFET performanceVSAvoidmetal migration
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The diffusion barrier layer acts as a mediator that protects the aluminum-containing work function adjustment material from diffusing into adjacent FETs. This intermediary layer (composed of Ti, Ta, W, Mo, or their compounds) allows the metal gate films to maintain their performance-enhancing properties while preventing the harmful metal migration that would otherwise degrade device reliability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The gate structure employs a composite material approach, combining the work function adjustment material (aluminum-containing) with a diffusion barrier material (Ti, Ta, W, Mo or their nitrides/oxides). This composite structure leverages the electrical properties of the aluminum-containing layer while using the barrier layer to prevent its harmful migration, achieving both performance and reliability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The diffusion barrier layer effectively isolates nearby FETs from aluminum diffusion, maintaining stable threshold voltages and improving device reliability and performance by preventing performance degradation due to metal migration.

Implementation Method 1

Incorporating a diffusion barrier layer at the surface of aluminum-containing work function adjustment material layers to prevent aluminum diffusion into adjacent FETs

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS11908915B2Method of manufacturing semiconductor devices and semiconductor devices
Publication Date: 2024.02.20 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11908915B2 patent drawing
  • US11908915B2 patent drawing
  • US11908915B2 patent drawing

AI summary

A semiconductor device includes a gate structure disposed over a channel region and a source/drain region. The gate structure includes a gate dielectric layer over the channel region, one or more work function adjustment material layers over the gate dielectric layer, and a metal gate electrode layer over the one or more work function adjustment material layers. The one or more work function adjustment layers includes an aluminum containing layer, and a diffusion barrier layer is disposed at at least one of a bottom portion and a top portion of the aluminum containing layer. The diffusion barrier layer is one or more of a Ti-rich layer, a Ti-doped layer, a Ta-rich layer, a Ta-doped layer and a Si-doped layer.