Aluminum Brazing Sheet Processing for Flux-Free Brazeability

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Solution Overview

Problem

Existing brazing methods for aluminum materials face issues such as flux residue, low productivity, and poor brazeability in vacuum-brazing, and flux-free methods suffer from poor brazeability due to the chemical compositions of core and filler materials.

Innovation Solution

A manufacturing method involving a clad slab with a core-material slab and a filler-material slab of Al—Si—Mg series alloy, followed by hot rolling, cold rolling, and etching with an inorganic acid etchant to enhance brazeability in an inert-gas atmosphere.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If flux-brazing method is used, then brazing can be performed easily, but flux and residue adhere to the surface causing quality problems and requiring additional acid-washing process

Engineering Contradiction:
Improvebrazing process easeVSAvoidflux residue on surface
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The invention extracts and eliminates the flux component from the brazing process by developing a flux-free brazing sheet with core material and filler material that enable brazing without flux, thereby removing the source of flux residue contamination

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention creates an inert environment by using specific alloy compositions (Al-Si-Mg series) that prevent oxidation and enable brazing in inert-gas atmosphere without requiring flux, thus avoiding flux residue problems

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Object-affected harmful factors

If vacuum-brazing method is used, then flux residue problems are avoided, but productivity decreases and equipment cost increases

Engineering Contradiction:
Improveflux residue eliminationVSAvoidbrazing productivity
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The brazing sheet is designed with self-protective properties through specific alloy compositions that enable effective brazing in inert-gas atmosphere without requiring vacuum conditions, allowing standard furnaces to be used and maintaining high productivity

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention changes the chemical composition parameters of the brazing sheet (using Al-Si-Mg series alloys with specific ranges of Si: 3-13 mass%, Mg: 0.1-2 mass%) to enable flux-free brazing in inert-gas atmosphere, achieving both flux residue elimination and high productivity

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional brazing sheet composition is used in flux-free brazing, then brazing can be performed without flux, but brazeability deteriorates

Engineering Contradiction:
Improveflux-free brazing capabilityVSAvoidbrazeability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention optimizes the chemical composition parameters of both core material and filler material, specifically using Al-Si-Mg series alloy with Si: 3-13 mass%, Mg: 0.1-2 mass%, to achieve excellent brazeability in flux-free brazing conditions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite structure with core material and filler material having different but complementary compositions, where the filler material (Al-Si-Mg series) specifically enhances brazeability by breaking down oxide films while the core material provides structural integrity

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces a brazing sheet with improved brazeability and reduced flux residue, maintaining high productivity and quality without the need for flux, while avoiding the drawbacks of vacuum-brazing.

Implementation Method 1

a surface of the clad sheet is etched using a liquid etchant that includes an inorganic acid

Methodology Applied
Scientific EffectEtching:

Implementation Method 2

These metal elements act to break down oxide films present on the brazing sheet itself and on the surface of the opposing material to be joined with the brazing sheet during brazing

Methodology Applied
Scientific EffectOxide film breakdown: Oxidation

Data Source

PatentUS12466004B2Method of manufacturing a brazing sheet
Publication Date: 2025.11.11 UACJ CORP
  • US12466004B2 patent drawing

AI summary

A brazing-sheet manufacturing method includes superposing a core-material slab on or adjacent to at least one surface of a filler-material slab to form a clad slab, the core-material slab being composed of an aluminum material and the filler-material slab being composed of an Al—Si—Mg series alloy. Then, the clad slab is hot rolled to form a clad sheet having a core material layer composed of the aluminum material of the core-material slab and a filler material layer composed of the Al—Si—Mg series alloy of the filler-material slab. Then, the clad sheet is subjected to one or more passes of cold rolling. Either between cold-rolling passes or after the completion of the cold rolling, a surface of the clad sheet is etched using a liquid etchant that includes one or more inorganic acids. The liquid etchant does not contain fluorine atoms.