Aluminum Composite Corrosion Protection Layer

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Solution Overview

Problem

Conventional aluminum composite materials for heat exchangers suffer from inadequate corrosion resistance, leading to significant mass loss and potential detachments under corrosive conditions, which compromises the service life and reliability of engines, especially in intercoolers and water coolers.

Innovation Solution

An aluminum composite material with a corrosion protection layer composed of an aluminum alloy with specific weight percentages of Si, Fe, Cu, Mn, Mg, Cr, Zn, and Ti, optimized to form a fine-grained recrystallized grain structure, is applied to the core layer, enhancing bonding properties and limiting corrosion spread.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional aluminum composite materials are used for heat exchangers, then manufacturing and processing are relatively simple, but corrosion resistance is inadequate leading to significant mass loss and potential detachments

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidmaterial loss
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent applies a multi-layer composite structure consisting of a core layer (AA3003 or AA3005 aluminum alloy) and a corrosion protection layer (AA5000 series aluminum alloy with 2-10% Mg). This composite material structure combines the good formability of the core layer with the superior corrosion resistance of the protection layer, achieving both manufacturing feasibility and enhanced corrosion protection against condensate attack in intercoolers

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters of the aluminum alloy by adding specific amounts of magnesium (2-10% by weight) and controlling other alloying elements (Mn: 0.05-2%, Si: 0.05-1%, Fe: 0.05-1%, Zn: 0.05-1%, Ti: 0.01-0.5%, B: 0.001-0.05%). These parameter changes transform the material properties to achieve significantly improved corrosion resistance while maintaining adequate formability for heat exchanger manufacturing

Inventive Principle:
Principle #35Parameter changes

2Productivity

If thinner wall thicknesses are used to reduce weight and cost, then productivity and efficiency improve, but the absolutely permissible depth of corrosion in the material becomes ever smaller

Engineering Contradiction:
Improvethin wall thickness capabilityVSAvoidcorrosion resistance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent uses a composite material structure where the corrosion protection layer (AA5000 series with 2-10% Mg) provides superior corrosion resistance, enabling the use of thinner wall thicknesses in the core layer without compromising the absolutely permissible depth of corrosion. The protection layer acts as a sacrificial barrier that prevents corrosion penetration into the thin-walled core structure

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The corrosion protection layer serves as a pre-applied protective barrier that cushions the thin-walled core layer against corrosive condensate attack. This beforehand protection allows the design to use thinner walls while maintaining adequate corrosion margins, as the protection layer absorbs the corrosive damage before it can affect the structural integrity of the thin core material

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides extreme low material loss and improved bonding, preventing coarse detachments even under extreme corrosive conditions, ensuring the structural integrity and longevity of heat exchanger components.

Implementation Method 1

the material of the core layer acts as a sacrificial anode

Methodology Applied
Scientific EffectGalvanic corrosion protection: Electrochemiluminescence

Implementation Method 2

optimized to form a fine-grained recrystallized grain structure

Methodology Applied
Scientific EffectRecrystallization: Crystallisation

Data Source

PatentEP3445520B1Aluminium compound with an Anti-corrosive layer
Publication Date: 2019.08.28 SPEIRA GMBH
  • EP3445520B1 patent drawingFigure 1
  • EP3445520B1 patent drawingFigure 2a~2b
  • EP3445520B1 patent drawingFigure 3

AI summary

The invention relates to an aluminum composite material, comprising at least one core layer (4) having an aluminum core alloy and at least one corrosion protection layer (6) provided on the core layer (4). The aim of specifying an aluminum composite material having further improved corrosion resistance, in particular to avoid coarse separations under corrosive conditions, is achieved in that the corrosion protection layer (6) has an aluminum alloy having the following composition in % by weight: Si ≤ 0.10 %, Fe ≤ 0.6 %, Cu ≤ 0.2 %, 0.9 % ≤ Mn ≤ 1.2 %, Mg ≤ 0.10 %, Cr ≤ 0.3 %, Zn ≤ 0.1 %, Ti ≤ 0.1 %, remainder Al and unavoidable contaminants, individually at most 0.05 %, in total at most 0.15 %. The invention further relates to a method for producing an aluminum composite materia (2), to a use, and to a heat exchanger, or to a component of a heat exchanger.