Aluminum Electrode Ferroelectric Substrate Cost Reduction

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Solution Overview

Problem

The development of cost-effective lead-free niobate-based ferroelectric thin-film devices is hindered by the need for suitable lamination structures and manufacturing processes, as well as the challenge of maintaining performance and properties while reducing costs, particularly with the use of materials like platinum and gold in existing piezoelectric devices.

Innovation Solution

A ferroelectric thin-film laminated substrate is created with a platinum or platinum alloy lower electrode, a sodium potassium niobate ferroelectric thin-film layer, an aluminum or aluminum alloy upper electrode, and an upper electrode intermediate layer made from metals with low oxidizability that form intermetallic compounds with aluminum, such as nickel, cobalt, tungsten, or molybdenum, to reduce costs while maintaining performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If platinum or gold electrodes are used in lead-free niobate-based ferroelectric thin-film devices, then the device performance and polarization properties are maintained, but the manufacturing cost increases

Engineering Contradiction:
Improvedevice performanceVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces expensive platinum and gold electrodes with cheaper aluminum electrodes in lead-free niobate-based ferroelectric thin-film devices. This substitution significantly reduces manufacturing costs while the patent ensures device performance is maintained through optimized aluminum electrode configurations and processing conditions

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent modifies electrode material parameters by transitioning from noble metals (Pt, Au) to aluminum, and adjusts processing parameters such as deposition conditions and heat treatment to optimize the aluminum electrode's performance. This parameter change enables cost reduction while preserving the necessary electrical and mechanical properties for device functionality

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If lead-free niobate-based materials are used instead of PZT, then environmental compliance is improved, but the available manufacturing processes and lamination structures are limited

Engineering Contradiction:
Improveenvironmental complianceVSAvoidmanufacturing process availability
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent adjusts manufacturing parameters including deposition temperature, oxygen partial pressure, and heat treatment conditions to enable successful fabrication of lead-free niobate-based thin films. These parameter optimizations overcome the immaturity of manufacturing processes for lead-free materials while maintaining device performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite structures combining lead-free niobate-based ferroelectric thin films with aluminum electrodes and appropriate buffer/adhesion layers. This composite approach addresses the limitations of lead-free materials by creating a synergistic structure that enables successful manufacturing while achieving environmental compliance

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the reduction of costs in niobate-based ferroelectric thin-film devices while maintaining their performance and properties, as demonstrated by the preservation of polarization properties in the thin-film devices.

Implementation Method 1

a part of the upper electrode intermediate layer and a part of the upper electrode layer are alloyed

Methodology Applied
Scientific EffectAlloying:

Implementation Method 2

Piezoelectric devices utilize the piezoelectric effect of a ferroelectric material, and are widely used as functional devices such as actuators and stress sensors

Methodology Applied
Scientific EffectPiezoelectric effect: Piezoelectric Effect

Implementation Method 3

Pyroelectric devices detect light (including infrared light) utilizing the pyroelectric effect of a ferroelectric material

Methodology Applied
Scientific EffectPyroelectric effect: Pyroelectric Effect

Data Source

PatentUS10497855B2Ferroelectric thin-film laminated substrate, ferroelectric thin-film device, and manufacturing method of ferroelectric thin-film laminated substrate
Publication Date: 2019.12.03 SUMITOMO CHEM CO LTD
  • US10497855B2 patent drawing

AI summary

There is provided a ferroelectric thin-film laminated substrate, including a substrate, and further including a lower electrode layer, a ferroelectric thin-film layer, an upper electrode intermediate layer, and an upper electrode layer being sequentially stacked on the substrate, in which: the lower electrode layer is made of platinum or a platinum alloy; the ferroelectric thin-film layer is made of a sodium potassium niobate (typical chemical formula of (K1-xNax)NbO3, 0.4≤x≤0.7); the upper electrode layer is made of aluminum or an aluminum alloy; the upper electrode intermediate layer is made of a metal that has less oxidizability than titanium and can generate an intermetallic compound with Aluminum; and a part of the upper electrode intermediate layer and a part of the upper electrode layer are alloyed.