Aluminum Paste for High-Concentration N-Type Semiconductor Diffusion

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Solution Overview

Problem

Existing methods for forming an n layer on semiconductor substrates are less productive and require excessive energy due to prolonged heating treatments, and they struggle to efficiently create a high concentration n+ layer.

Innovation Solution

A paste composition containing aluminum powder, a compound with an n-type dopant element (phosphorus, antimony, or bismuth), and a resin, where the n-type dopant element content is between 1.5 and 1000 parts by mass per 100 parts of aluminum, enabling the formation of a high-concentration diffusion layer on semiconductor substrates in a short time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If prolonged heating treatment is performed to form an n layer, then the n layer is formed on the semiconductor substrate, but the productivity decreases and energy consumption increases

Engineering Contradiction:
Improveformation of n layerVSAvoidproduction efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The invention changes the chemical composition parameters of the paste by incorporating specific compounds containing n-type dopant elements (phosphorus, antimony, arsenic, or bismuth) in controlled amounts (1.5-1000 parts by mass per 100 parts aluminum). This compositional modification enables the formation of n layers with high dopant concentration through shorter heating times, thus improving productivity while maintaining reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite paste material combining aluminum powder with compounds containing n-type dopant elements, resins, and solvents. This composite formulation allows simultaneous achievement of good printability (from aluminum powder) and high-concentration dopant introduction (from the dopant compounds), enabling efficient n layer and n+ layer formation with reduced processing time

Inventive Principle:
Principle #40Composite materials

2Reliability

If prolonged heating treatment is performed to form an n layer, then the n layer is formed on the semiconductor substrate, but the energy consumption increases

Engineering Contradiction:
Improveformation of n layerVSAvoidheating energy
Core Design Contradiction:
ReliabilityVSUse of energy by stationary object

Solution Approach 1:

By modifying the paste composition to include compounds with n-type dopant elements in specific concentrations, the invention reduces the heating time required to achieve the desired dopant concentration in the semiconductor substrate. This parameter change in composition directly translates to reduced energy consumption while maintaining the reliability of n layer formation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The dopant elements are pre-incorporated into the paste composition in the desired concentration ranges before application to the substrate. This preliminary preparation of the paste with optimized dopant content allows the heating process to be shorter and more efficient, reducing the energy required compared to conventional methods that require prolonged heating to achieve the same dopant concentration

Inventive Principle:
Principle #10Preliminary action

3Reliability

If conventional methods are used to form an n+ layer, then the n+ layer can be formed, but the process is complex and time-consuming

Engineering Contradiction:
Improveformation of n+ layerVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention merges the functions of aluminum paste application and n-type dopant introduction into a single paste composition. By combining aluminum powder with compounds containing n-type dopant elements in specific ratios, the process simplifies to a single application and heating step, eliminating the need for separate dopant introduction steps and reducing overall process complexity while maintaining the ability to form high-concentration n+ layers

Inventive Principle:
Principle #5Merging (Combining)

4Reliability

If conventional methods are used to form an n+ layer, then the n+ layer can be formed, but the processing time increases

Engineering Contradiction:
Improveformation of n+ layerVSAvoidprocessing time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The invention optimizes the concentration of n-type dopant elements in the paste composition (1.5-1000 parts by mass per 100 parts aluminum) to achieve high dopant concentration in the resulting n+ layer. This parameter optimization enables faster diffusion and more rapid formation of high-concentration dopant regions, significantly reducing processing time while maintaining the reliability of n+ layer formation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The paste composition allows for the simple and efficient formation of a diffusion layer with a high concentration of n-type dopant elements on semiconductor substrates, reducing processing time and energy consumption while enhancing the efficiency of semiconductor devices like solar cells.

Implementation Method 1

forming a diffusion layer with a high concentration of n-type dopant element on a semiconductor substrate

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS10446291B2Paste composition
Publication Date: 2019.10.15 TOYO ALUMINIUM KK
  • US10446291B2 patent drawing
  • US10446291B2 patent drawing

AI summary

Provided is a paste composition that enables the formation of a diffusion layer with a high concentration of n-type dopant element on a semiconductor substrate in a simple manner. The paste composition is intended to form a film on a semiconductor substrate. The paste composition contains an aluminum powder, a compound containing an n-type dopant element, a resin, and a solvent. The n-type dopant element is one, two, or more elements selected from the group consisting of phosphorus, antimony, arsenic, and bismuth. The content of the n-type dopant element in the n-type dopant element-containing compound is 1.5 parts by mass or more and 1000 parts by mass or less, per 100 parts by mass of aluminum contained in the aluminum powder.