Aluminum-Plated Steel Sheet for Coating Adhesion After Hot Stamping

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Solution Overview

Problem

Existing aluminum-plated steel sheets for hot stamping lack sufficient corrosion resistance after coating, primarily due to inadequate adhesion of the coating material and insufficient reactivity between the oxide film and chemical conversion agents.

Innovation Solution

An aluminum-plated steel sheet with a plating layer containing specific A group elements (such as Be, Mg, Ca, Sr, Ba, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn) and a controlled average grain size, which enhances the adhesion of the electrodeposition coating film and improves corrosion resistance after coating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of moving object

If the sheet thickness of steel sheets is reduced to reduce weight, then the weight of vehicle bodies is reduced, but the strength of structures decreases

Engineering Contradiction:
Improveweight of vehicle bodiesVSAvoidstrength of structures
Core Design Contradiction:
Weight of moving objectVSStrength

Solution Approach 1:

The patent applies parameter changes by heating the steel sheet to high temperature (Ac3 transformation point or higher) to alter its microstructure and enable forming, then rapidly cooling it to achieve martensitic transformation and high strength. This thermal parameter change allows thin sheets to achieve both formability and high strength simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes phase transitions of steel during hot stamping: heating transforms the microstructure to austenite, enabling plastic deformation; rapid cooling then transforms it to martensite, achieving high strength. This phase transition mechanism resolves the contradiction between thinning for weight reduction and maintaining strength

Inventive Principle:
Principle #36Phase transitions

2Weight of moving object

If the sheet thickness of steel sheets is reduced to reduce weight, then the weight of vehicle bodies is reduced, but the formability of the material deteriorates

Engineering Contradiction:
Improveweight of vehicle bodiesVSAvoidformability of material
Core Design Contradiction:
Weight of moving objectVSEase of operation

Solution Approach 1:

The patent changes the temperature parameter of the steel sheet from ambient to high temperature (Ac3 point or higher), which fundamentally alters the material's formability. At elevated temperature, the steel sheet becomes soft and easily formable, allowing complex shapes to be achieved even with reduced thickness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent exploits the phase transition from ferrite/pearlite to austenite upon heating, which dramatically improves ductility and formability. This phase change enables thin sheets to be formed into complex shapes without cracking or thinning during the forming process

Inventive Principle:
Principle #36Phase transitions

3Reliability

If a chemical conversion film is formed on the surface of hot-stamped members to improve corrosion resistance, then the adhesion of coating material is insufficient, but corrosion resistance is required

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidadhesion of coating material
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the chemical composition parameters of the plating layer by adding specific elements (Al: 5-15 mass%, Si: 3-15 mass%, Mn: 0.5-3.0 mass%) to create a plating layer with enhanced reactivity. This compositional parameter change ensures both good adhesion and corrosion resistance after hot stamping and coating

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite plating layer structure containing multiple elements (Al-Si-Mn system) that work synergistically: Al provides base protection, Si enhances oxidation resistance and reactivity, and Mn improves adhesion. This composite material approach resolves the contradiction between adhesion and corrosion resistance

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution significantly improves the adhesion of the electrodeposition coating film and enhances the corrosion resistance after coating of hot-stamped members, making the aluminum-plated steel sheet more suitable for applications in the vehicle manufacturing industry.

Implementation Method 1

a surface layer area of a plated steel sheet before hot stamping, and the proportion of A group elements in an oxide film layer that is formed on a surface of a hot-stamped member

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

a material that is a forming subject is heated to a high temperature, and a steel sheet softened by heating is formed by pressing and, after the forming (or almost at the same time as the forming), cooled

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

the mechanical strength of the material can be increased by the quenching effect of the cooling after forming

Methodology Applied
Scientific EffectQuenching: Cooling

Data Source

PatentUS12234538B2Aluminum-plated steel sheet, hot-stamped member, and method for manufacturing hot-stamped member
Publication Date: 2025.02.25 NIPPON STEEL CORPORATION
  • US12234538B2 patent drawing
  • US12234538B2 patent drawing
  • US12234538B2 patent drawing

AI summary

This aluminum-plated steel sheet has a steel sheet and a plating layer formed on a surface of the steel sheet, the plating layer contains one or more A group elements selected from a group consisting of Be, Mg, Ca, Sr, Ba, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn, a remainder of Al, Fe, and impurities, a thickness t of the plating layer is 10 to 60 μm, and an average grain size is 2t/3 or less and 15 μm or less in a thickness range from an outermost surface of the plating layer to a ⅔ thickness t position.