Aluminum Wire Polyimide Insulation Adhesion

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Solution Overview

Problem

Aluminum-based insulated wires face issues with poor adhesion between the conductor and insulating film, as well as reduced processing resistance due to oxidation and lower melting points compared to copper-based wires, limiting their use in miniaturized electronic devices.

Innovation Solution

A polyimide resin insulating film is applied to an aluminum conductor, composed of specific ratios of 3,3′,4,4′-biphenyl tetracarboxylic acid dianhydride, 3,3′,4,4′-benzophenone tetracarboxylic acid dianhydride, and pyromellitic anhydride reacted with 4,4′-diaminodiphenyl ether, providing excellent adhesion and environmental resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of moving object

If aluminum conductor is used to reduce weight, then weight reduction is achieved, but adhesion between conductor and insulating film deteriorates

Engineering Contradiction:
Improveweight of coilVSAvoidadhesion between conductor and insulating film
Core Design Contradiction:
Weight of moving objectVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the polyimide resin by controlling the molar ratios of specific acid components (3,3′,4,4′-biphenyl tetracarboxylic acid dianhydride, 3,3′,4,4′-benzophenone tetracarboxylic acid dianhydride, and pyromellitic anhydride) to optimize adhesion to aluminum conductor while maintaining the weight reduction benefit of using aluminum instead of copper

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system consisting of aluminum conductor combined with a specifically formulated polyimide resin insulating film, where the composite achieves both light weight and excellent adhesion through the optimized resin composition

Inventive Principle:
Principle #40Composite materials

2Weight of moving object

If aluminum conductor is used instead of copper, then weight reduction is achieved, but processing resistance deteriorates

Engineering Contradiction:
Improveweight of coilVSAvoidprocessing resistance
Core Design Contradiction:
Weight of moving objectVSEase of manufacture

Solution Approach 1:

The patent optimizes the chemical composition parameters of the polyimide resin, specifically controlling the content of pyromellitic anhydride and other acid components, to enhance processing resistance of the insulating film on aluminum conductor, thereby improving ease of manufacture while maintaining weight reduction

Inventive Principle:
Principle #35Parameter changes

3Weight of moving object

If aluminum conductor is used, then weight reduction is achieved, but oxidation resistance worsens

Engineering Contradiction:
Improveweight of coilVSAvoidoxidation resistance
Core Design Contradiction:
Weight of moving objectVSObject-affected harmful factors

Solution Approach 1:

The patent forms a composite protective structure where the optimized polyimide resin insulating film serves as a protective layer on the aluminum conductor, providing oxidation resistance while the aluminum core maintains the weight reduction advantage

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition of the polyimide resin by adjusting the ratios of aromatic acid components to enhance the chemical stability and oxidation resistance of the insulating film, thereby protecting the aluminum conductor from oxidation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances adhesion and processing resistance of the insulating film on aluminum conductors, maintaining performance even under thermal degradation, and supports miniaturization of coils while offering excellent insulating, electric, and mechanical properties.

Implementation Method 1

a first insulating film provided on the aluminum conductor. The first insulating film is made of a first polyimide obtained by reacting an acid component containing 50 mol % to 90 mol % of 3,3′,4,4′-biphenyl tetracarboxylic acid dianhydride, 5 mol % to 20 mol % of 3,3′,4,4′-benzophenone tetracarboxylic acid dianhydride, and 5 mol % to 40 mol % of pyromellitic anhydride with a diamine component containing 4,4′-diaminodiphenyl ether

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS9972409B2Insulated wire
Publication Date: 2018.05.15 SHOWA ELECTRIC WIRE & CABLE CO LTD
  • US9972409B2 patent drawing
  • US9972409B2 patent drawing
  • US9972409B2 patent drawing

AI summary

According to one embodiment, an insulated wire is disclosed. The insulated wire includes an aluminum conductor, and a first insulating film provided on the aluminum conductor. The first insulating film is made of a first polyimide obtained by reacting an acid component containing 50 mol % to 90 mol % of 3,3′,4,4′-biphenyl tetracarboxylic acid dianhydride, 5 mol % to 20 mol % of 3,3′,4,4′-benzophenone tetracarboxylic acid dianhydride, and 5 mol % to 40 mol % of pyromellitic anhydride with a diamine component containing 4,4′-diaminodiphenyl ether.