Amide Taggants for Lubricant Authentication via Immunoassay

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Solution Overview

Problem

The petroleum industry faces challenges in authenticating and identifying lubricating engine oils due to product counterfeiting and adulteration, where counterfeit products can appear visually identical to genuine ones, leading to financial losses and performance issues.

Innovation Solution

The use of taggants comprising one or more amide compounds, specifically aliphatic and cyclic amide compounds, in conjunction with immunoassays provides a method for authenticating and identifying lubricating engine oils by creating a unique chemical signature that can be detected using lateral flow immunoassays, preventing counterfeiting and adulteration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If visual markers are used to distinguish genuine products, then product identification is improved, but counterfeiters can replicate the visual appearance making authentication unreliable

Engineering Contradiction:
Improveproduct identification accuracyVSAvoidauthentication reliability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent extracts the authentication function from visual markers and relocates it to chemical taggants embedded in the product. Instead of relying on external visual indicators that can be copied, the authentication is moved to the product's chemical composition itself through embedded amide compounds that serve as unique molecular fingerprints.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces immunoassay technology as an intermediary detection mechanism. Antibodies specific to the amide taggants act as mediators between the product and the detection system, enabling highly specific identification that cannot be replicated by visual copying alone.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If chemical taggants are used for product authentication, then authentication reliability is improved, but detection complexity increases

Engineering Contradiction:
Improveauthentication reliabilityVSAvoiddetection system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent replaces complex instrumental analysis methods with immunoassay-based detection. Instead of using sophisticated chemical analysis equipment to identify taggants, the system uses biological antibodies that naturally and specifically bind to the amide compounds, simplifying the detection mechanism while maintaining high reliability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent employs visual color changes as the detection output of the immunoassay. The antibody-taggant interaction produces a colorimetric signal that can be easily observed and interpreted, converting a complex biochemical recognition event into a simple visual readout that reduces detection complexity.

Inventive Principle:
Principle #32Color changes

3Stability of the object's composition

If amide compounds are used as taggants, then thermal and oxidative stability is improved, but compatibility with additives must be ensured

Engineering Contradiction:
Improvethermal and oxidative stabilityVSAvoidadditive compatibility
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The patent modifies the chemical parameters of the taggant molecules by selecting specific amide compounds with appropriate molecular structures, functional groups, and physical properties. This allows optimization of both stability characteristics and compatibility with lubricant additives through careful molecular design and selection.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite authentication system where amide taggants are integrated into the lubricant formulation alongside performance additives. The taggants and additives coexist in a compatible manner, with the amide compounds serving dual purposes as both functional lubricant components and authentication markers.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively distinguishes genuine from counterfeit lubricating engine oils, ensuring product authenticity and preventing financial losses by providing a robust, thermally stable, and oxidatively stable chemical marker that is compatible with additives, thus enhancing security and quality assurance.

Implementation Method 1

an immunoassay specific for the taggant

Methodology Applied
Scientific EffectImmunoassay: Absorption (physical)

Implementation Method 2

detected using lateral flow immunoassays

Methodology Applied
Scientific EffectLateral flow: Capillary Action

Data Source

PatentEP3237903B1Methods for authentication and identification of petroleum products
Publication Date: 2020.02.26 EXXONMOBIL TECHNOLOGY & ENGINEERING CO
  • EP3237903B1 patent drawingFigure 1
  • EP3237903B1 patent drawingFigure 2
  • EP3237903B1 patent drawingFigure 3

AI summary

A method is provided that associates a taggant with a product to produce a signature product. The taggant, when associated with the signature product, is visually undetectable; and comprises one or more amide compounds (e.g., a taggant array that comprises two or more amide compounds). The method also identifies the taggant in the signature product by an immunoassay specific for the taggant; maps the taggant of the signature product to a batch code of the signature product; obtains a test product to determine authenticity or identity of the test product; identifies the presence or absence of a taggant in the test product by an immunoassay specific for the taggant; and compares results of the immunoassay carried out on the test product with results of the immunoassay carried out on the signature product to determine authenticity or identity of the test product. Lubricating engine oils are provided containing the taggant.