Amine Additive System for Warm Bituminous Mixes

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Solution Overview

Problem

Current methods for reducing the manufacturing temperature of hot bituminous mixes do not sufficiently lower the temperature while maintaining the mechanical properties of the mixes, and often require significant modifications to traditional processes.

Innovation Solution

An additive system comprising alkylamidopolyamines, alkylimidazolines, and ethoxylated fatty acids is added to the bitumen, reducing the manufacturing and implementation temperatures of hot mixes by up to 50°C without degrading the mechanical properties, achieved by mixing the additives with the hydrocarbon binder before application.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If traditional hot mix manufacturing processes are used, then the mechanical properties and workability of the bituminous mixture are maintained, but the manufacturing temperature is high (140-175°C) leading to high energy consumption and environmental impact

Engineering Contradiction:
Improvemanufacturing temperatureVSAvoidenergy consumption
Core Design Contradiction:
TemperatureVSUse of energy by moving object

Solution Approach 1:

The invention changes the chemical composition parameters of the bitumen by adding a specific system of additives (amine-type surfactants, ethoxylated fatty acids, and their reaction products) to modify the rheological properties of the binder, enabling workable mixtures at lower temperatures without sacrificing mechanical performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite bituminous binder system by combining traditional bitumen with a multi-component additive system comprising amine-type surfactants, ethoxylated fatty acids, and their reaction products, where the synergistic interaction of components enables temperature reduction while maintaining mixture properties

Inventive Principle:
Principle #40Composite materials

2Temperature

If manufacturing temperature is reduced to lower energy consumption, then environmental impact is reduced, but the mechanical properties and workability of the mixture deteriorate

Engineering Contradiction:
Improvemanufacturing temperatureVSAvoidmechanical properties
Core Design Contradiction:
TemperatureVSStrength

Solution Approach 1:

The additive system modifies the chemical and rheological parameters of the bitumen binder, changing its viscosity-temperature relationship to maintain adequate binding strength and mixture workability at reduced manufacturing temperatures of 90-120°C

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The amine-type surfactants and ethoxylated fatty acids act as intermediary substances that improve the interaction between bitumen and aggregates at lower temperatures, ensuring adequate adhesion and mechanical properties without requiring high thermal energy

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If bitumen viscosity is reduced by heating, then workability and wettability with aggregates are improved, but energy consumption increases and environmental harm is caused

Engineering Contradiction:
ImproveworkabilityVSAvoidgreenhouse gas emissions
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The invention changes the chemical composition of the bitumen binder by incorporating amine-type surfactants and ethoxylated fatty acids that modify the viscosity characteristics, allowing the binder to achieve adequate workability and wettability at lower temperatures without requiring intensive heating that generates greenhouse gases

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The additive system allows for the production and application of warm mixes at 30 to 50°C lower temperatures than traditional hot mixes, maintaining or improving mechanical properties and adhering to standard processes, thus reducing energy consumption and environmental impact.

Implementation Method 1

additive system based on amine-type surfactant used to manufacture hot-applied bituminous mixtures having a lowered manufacturing temperature

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

the presence of this particular additive system, can be manufactured and implemented at temperatures 30 to 50° lower

Methodology Applied
Scientific EffectRheology modification:

Data Source

PatentEP2396286B1System of additives for the preparation of a warm mix for road use based on an amine-type surfactant
Publication Date: 2018.10.24 COLAS LTD
  • EP2396286B1 patent drawing
  • EP2396286B1 patent drawing
  • EP2396286B1 patent drawing

AI summary

The present invention relates to a system of additives for the preparation of a warm mix for road use comprising: one or more components (A) chosen from adhesion dopes, and one or more components (B) chosen from ethoxylated fatty (poly)amines and ethoxylated fatty amido(poly)amines. The invention also relates to the hydrocarbon-based binder and the bituminous mixes comprising said system of additives.