Amine-Based Compound for OLED Emission Layer Efficiency

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current organic light-emitting devices face challenges in achieving low driving voltage, high efficiency, and long lifespan due to intermolecular gathering issues in emission layers, which affect light emission efficiency.

Innovation Solution

Incorporating an amine-based compound represented by Formula 1, which includes a cyclopentaphenanthrene group, in the emission layer to hinder intermolecular gathering and enhance light emission efficiency, with the compound being synthesized using suitable organic synthesis methods and disposed between electrodes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional emission layers are used, then device structure is simple, but light emission efficiency is low due to intermolecular gathering

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidcompound structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent introduces a 3-dimensional obstacle effect by incorporating a cyclopentaphenanthrene group into the emission layer compound structure. This three-dimensional structural element physically blocks intermolecular gathering and aggregation of emission molecules, thereby preventing efficiency loss while maintaining a relatively simple molecular design approach.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Productivity

If emission layer materials are optimized for high efficiency, then light emission efficiency improves, but driving voltage increases

Engineering Contradiction:
Improvelight emission efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The patent modifies molecular parameters by selecting specific substituents (R1-R10, R31-R34) with different electronic properties, steric effects, and molecular weights. By changing these molecular parameters within the general formula framework, the invention optimizes the balance between light emission efficiency and driving voltage characteristics.

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If emission layer density is increased for higher brightness, then brightness improves, but lifespan decreases due to molecular aggregation

Engineering Contradiction:
ImprovebrightnessVSAvoiddevice lifespan
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The cyclopentaphenanthrene group acts as a steric intermediary or spacer between emission molecules. This intermediary structure maintains appropriate molecular spacing, preventing harmful aggregation while allowing sufficient emission material density to achieve high brightness, thereby extending device lifespan.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organic light-emitting device exhibits low driving voltage, high brightness, and long lifespan with improved light emission efficiency due to the amine-based compound's 3-dimensional obstacle effect and flat structure.

Implementation Method 1

The organic light-emitting device exhibits low driving voltage, high brightness, and long lifespan with improved light emission efficiency due to the amine-based compound's 3-dimensional obstacle effect and flat structure.

Methodology Applied
Scientific Effect3-dimensional obstacle effect:

Implementation Method 2

Carriers, such as holes and electrons, may be recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10193074B2Amine-based compound and organic light-emitting device including the same
Publication Date: 2019.01.29 SAMSUNG DISPLAY CO LTD
  • US10193074B2 patent drawing
  • US10193074B2 patent drawing
  • US10193074B2 patent drawing

AI summary

A compound and an organic light-emitting device including the same, the compound being represented by Formula 1 below: