Amine Alkaline Fuel Cell Electrolyte for CO2 and Water Dilution

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Solution Overview

Problem

Conventional alkaline fuel cells face performance degradation due to reactions with carbon dioxide and water dilution, leading to increased costs and reduced effectiveness.

Innovation Solution

Incorporating an amine compound in the alkaline solution as the electrolyte and using carbon cloth coated with catalysts for the electrodes, along with a membrane separator and a system for separating water from the amine compound, helps maintain electrolyte concentration and extend fuel cell life.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional alkaline fuel cells use standard alkaline solution, then the fuel cell structure is simple, but the electrolyte dilutes due to water reactions leading to performance degradation

Engineering Contradiction:
Improvefuel cell performance stabilityVSAvoidelectrolyte composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses a composite electrolyte system combining amine compound and alkaline solution, where the amine compound (e.g., triethylamine) forms a separate phase that prevents water dilution of the active electrolyte, maintaining performance stability while managing the complexity through functional material combination

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional alkaline fuel cells operate normally, then power generation function is achieved, but carbon dioxide reacts with electrolyte causing performance degradation

Engineering Contradiction:
Improveresistance to carbon dioxideVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent converts the harmful reaction between carbon dioxide and conventional alkaline electrolyte into a beneficial system where carbon dioxide preferentially reacts with water in the aqueous phase, protecting the amine-based active electrolyte from degradation and extending fuel cell life

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Ease of manufacture

If cost-effective catalysts are used, then manufacturing cost is reduced, but catalytic activity may be insufficient

Engineering Contradiction:
Improvecatalyst costVSAvoidelectrical energy generation efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent optimizes catalyst parameters by using carbon cloth substrates with specific surface areas and implementing controlled catalyst coating processes, achieving cost-effective catalyst utilization that maintains sufficient catalytic activity for efficient electrical energy generation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances the performance and longevity of fuel cells by reducing electrolyte dilution and using cost-effective catalysts, resulting in efficient and durable alkaline fuel cells.

Implementation Method 1

The alkaline solution includes an amine compound... helps maintain electrolyte concentration

Methodology Applied
Scientific EffectPhase separation:

Implementation Method 2

at least one of the anode and the cathode comprises a carbon cloth coated with a catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

uses hydrogen and oxygen to generate electricity through an electrochemical reaction

Methodology Applied
Scientific EffectElectrochemical reaction:

Implementation Method 4

a system for separating water from the amine compound

Methodology Applied
Scientific EffectMembrane separation: Semipermeable Membrane

Data Source

PatentUS20240282980A1Alkaline amine fuel cell
Publication Date: 2024.08.22 UTAH VALLEY UNIVERSITY
  • US20240282980A1 patent drawing
  • US20240282980A1 patent drawing
  • US20240282980A1 patent drawing

AI summary

A fuel cell includes an anode, a cathode, and an electrolyte disposed between the anode and the cathode. The electrolyte includes an alkaline solution. The alkaline solution includes an amine compound. A plurality of fuel cells may be connected in series to provide a fuel cell stack with a plate disposed between the anode of a first fuel cell of two adjacent fuel cells of the plurality of fuel cells and the cathode of a second fuel cell of the two adjacent fuel cells of the plurality of fuel cells.