Amine Compound Hole Transport Layer for OLED Efficiency

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Solution Overview

Problem

Current organic electroluminescence devices face challenges in achieving high emission efficiency and longevity due to limitations in materials used for the hole transport region, which affect the overall performance and stability of the luminescence device.

Innovation Solution

Incorporating a specific amine compound in the hole transport region of the luminescence device, represented by Formula 1, which allows for improved hole transport and electron blocking, enhancing the device's efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional materials are used in the hole transport region, then the device structure is simple and manufacturing is easier, but the emission efficiency and device life are insufficient

Engineering Contradiction:
Improveemission efficiencyVSAvoidmaterial complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure of amine compounds by changing parameters such as substituting hydrogen atoms with deuterium atoms, replacing carbon atoms with nitrogen atoms in aromatic rings, and adjusting the number and position of substituent groups. These parameter changes in the chemical structure improve hole transport capability and electron blocking performance, thereby increasing emission efficiency and device lifetime without fundamentally changing the device architecture.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material strategies by combining the newly developed amine compound with other functional materials in the hole transport region. The amine compound is used in conjunction with hole injection layers, hole transport layers, and electron blocking layers, creating a multi-layer composite structure that synergistically improves overall device performance while addressing the limitations of single-material systems.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If conventional hole transport materials are used, then the device manufacturing process is simpler, but the device life and stability are reduced

Engineering Contradiction:
Improvedevice lifeVSAvoidmanufacturing simplicity
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The patent extends device life by changing chemical parameters of the amine compound, including introducing deuterium atoms to slow down degradation reactions, adding sterically hindered substituent groups to protect the core structure from degradation, and optimizing the electronic structure to improve stability. These parameter changes maintain compatibility with existing manufacturing processes while significantly improving device lifetime and operational stability.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If existing materials are used in the hole transport region, then the device structure remains simple, but the overall performance and stability are limited

Engineering Contradiction:
Improvedevice stabilityVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent enhances device reliability by systematically changing molecular parameters of the amine compound, including optimizing the core aromatic structure, adjusting substituent positions and types, and modifying molecular weight and polarity. These parameter optimizations improve hole transport efficiency, electron blocking capability, and overall device stability without requiring fundamental redesign of the device architecture, thus maintaining relative simplicity while achieving superior performance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the amine compound in the hole transport region leads to increased emission efficiency and extended device life, addressing the limitations of existing materials and improving the overall performance of the luminescence device.

Implementation Method 1

a hole transport region disposed on the first electrode, an emission layer disposed on the hole transport region

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

which allows for improved hole transport and electron blocking, enhancing the device's efficiency and lifespan

Methodology Applied
Scientific EffectElectron blocking: Electrical Resistance

Data Source

PatentUS20220115598A1Luminescence device and amine compound for luminescence device
Publication Date: 2022.04.14 SAMSUNG DISPLAY CO LTD
  • US20220115598A1 patent drawing
  • US20220115598A1 patent drawing
  • US20220115598A1 patent drawing

AI summary

A luminescence device of an embodiment includes a first electrode, a hole transport region disposed on the first electrode, an emission layer disposed on the hole transport region, an electron transport region disposed on the emission layer, and a second electrode disposed on the electron transport region. The hole transport region includes an amine compound represented by Formula 1, thereby providing high emission efficiency.