Amine-Based Hole Transport Material for OLED Efficiency

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Solution Overview

Problem

Current organic light-emitting devices face challenges in achieving optimal hole mobility and preventing efficiency and lifespan reduction due to hole traps, which affect the performance and longevity of the devices.

Innovation Solution

An amine-based compound represented by Formula 1 is introduced, featuring a substituted or unsubstituted C6-C20 aromatic ring and electron donating groups, which is used in the hole transport region to enhance hole mobility and prevent reduction in efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional hole transport materials are used, then device structure is simple, but hole mobility is insufficient and hole traps reduce efficiency and lifespan

Engineering Contradiction:
Improvedevice efficiency and lifespanVSAvoidcompound structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the molecular parameters of hole transport materials by introducing specific amine-based compounds with tailored substituents (Ar1, Ar2, L1-L5) and molecular weights (200-500 g/mol). These parameter changes optimize hole mobility while maintaining thermal stability, resolving the contradiction between device reliability and structural complexity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite amine-based compounds combining aromatic rings (A), heterocyclic groups (X1, X2), and various substituents (R1-R4). This composite structure integrates multiple functional groups that work synergistically to improve hole transport while preventing trap formation, thereby enhancing reliability without excessive complexity.

Inventive Principle:
Principle #40Composite materials

2Speed

If hole mobility is enhanced using traditional materials, then charge transport improves, but efficiency and lifespan are reduced due to hole traps

Engineering Contradiction:
Improvehole mobilityVSAvoiddevice efficiency and lifespan
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent converts the potential harm of high hole mobility (which can lead to trap formation and efficiency loss) into a benefit by designing amine-based compounds that maintain high mobility while incorporating trap-preventing structural features. The specific molecular architecture transforms the speed advantage into a reliable performance characteristic.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The invention introduces localized functional groups (amine groups, aromatic substituents) at specific positions within the molecule to create local regions that facilitate hole transport while simultaneously preventing trap formation. This local quality enhancement resolves the contradiction between speed and reliability.

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If simple hole transport materials are used, then manufacturing is easier, but hole traps form reducing device performance

Engineering Contradiction:
Improvematerial synthesis easeVSAvoiddevice efficiency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent segments the hole transport function into distinct molecular components (core aromatic structure, amine groups, substituents) that can be synthesized separately and assembled. This segmentation maintains manufacturing ease while enabling precise control over hole transport properties and trap prevention, thereby improving device efficiency.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The amine-based compound improves hole mobility and prevents efficiency and lifespan reduction, leading to enhanced performance and longevity of organic light-emitting devices by effectively managing hole traps.

Implementation Method 1

Holes provided from the first electrode may move toward the emission layer through the hole transport region

Methodology Applied
Scientific EffectHole transport:

Implementation Method 2

Carriers, such as holes and electrons, may be recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10224491B2Amine-based compound and organic light-emitting device including the same
Publication Date: 2019.03.05 SAMSUNG DISPLAY CO LTD
  • US10224491B2 patent drawing
  • US10224491B2 patent drawing
  • US10224491B2 patent drawing

AI summary

An amine-based compound and an organic light-emitting device, the amine-based compound being represented by the following Formula 1: