Amine-Based Interlayer for OLED Thermal Resistance and Charge Balance

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Solution Overview

Problem

Current organic light-emitting devices (OLEDs) face challenges in achieving high thermal resistance and charge balance, which affect their efficiency and lifespan, particularly due to limitations in the materials used in the interlayer and electrode structures.

Innovation Solution

Incorporating an amine-based compound represented by Formula 1, which includes specific groups and substituents, into the interlayer of OLEDs to enhance thermal resistance, charge injection, and charge balance, thereby improving the device's mobility and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional materials are used in the interlayer and electrode structures of OLEDs, then the device can be manufactured with standard processes, but the thermal resistance and charge balance performance are insufficient

Engineering Contradiction:
Improvethermal resistance and charge balanceVSAvoidmaterial selection flexibility
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent modifies the chemical structure parameters of the interlayer materials by introducing specific amine-based compounds with defined molecular formulas (Formula 1 and Formula 2), substituent groups (R1, R2, R3, R10a), and structural parameters (a1, a2, a3, L1, L2, L3). These parameter changes optimize thermal resistance and charge balance while maintaining compatibility with standard OLED manufacturing processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures by combining the amine-based compound (Formula 1 or Formula 2) with specific functional groups and substituent patterns within the interlayer. This composite approach creates materials with enhanced thermal and electrical properties that simultaneously improve reliability without compromising manufacturability

Inventive Principle:
Principle #40Composite materials

2Productivity

If the interlayer materials are optimized for high thermal resistance and charge balance, then device efficiency and lifespan improve, but the device complexity increases due to specialized material requirements

Engineering Contradiction:
Improvedevice efficiency and lifespanVSAvoidmaterial structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The amine-based compounds described in Formula 1 and Formula 2 serve multiple functions simultaneously: they provide thermal resistance, facilitate charge injection, maintain charge balance, and ensure proper layer adhesion. This multi-functionality reduces the need for separate specialized materials, thereby improving device efficiency and lifespan without proportionally increasing complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent introduces specific local structural features (amine groups, aromatic rings, substituent patterns) at critical positions within the interlayer molecules. These localized structural modifications target specific performance aspects (thermal resistance, charge transport) without requiring complete redesign of the entire material system, thus improving productivity with controlled complexity increase

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the amine-based compound results in OLEDs with low driving voltage, high efficiency, and extended lifespan by optimizing thermal resistance and charge transport properties.

Implementation Method 1

an amine-based compound... to enhance thermal resistance, charge injection, and charge balance, thereby improving the device's mobility

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transition from an excited state to a ground state to thereby generate light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20220293862A1Light-emitting device including amine-based compound, electronic apparatus including the light-emitting device, and the amine-based compound
Publication Date: 2022.09.15 SAMSUNG DISPLAY CO LTD
  • US20220293862A1 patent drawing
  • US20220293862A1 patent drawing
  • US20220293862A1 patent drawing

AI summary

A light-emitting device including an amine-based compound, an electronic apparatus including the light-emitting device, and an amine-based compound represented by Formula 1 are provided:wherein the detailed description of Formula 1 is the same as described in the present specification.